利用循环伏安曲线研究了Ni2、Sn2络合离子的电沉积过程,在镍网基体上采用恒电位法电沉积制备了Ni-Sn合金.室温条件下,在30％ KOH溶液中测试纯镍、雷尼-Ni和Ni-Sn合金电极的阴极极化曲线,比较三种电极的催化析氢性能.结果表明,Ni-Sn合金可以提高镍的催化析氢性能.在室温25℃,阴极极化电流密度20 A/dm2和30 A/dm2时,Ni-Sn合金电极的析氢过电位分别为137 mV和161 mV,低于雷尼-Ni电极的299 mV和341 mV.
参考文献
| [1] | Arul Raj I;Venkatesan V K .Characterization of nickelmolybdenum and nickel-molybdenum-iron ally coating as cathodes for alkaline water electrolysis[J].International Journal of Hydrogen Energy,1988,13(4):215-223. |
| [2] | 刘萍,唐致远,宋全生,赵孟,王媛媛.Ni-Mo合金电极的制备条件对其析氢性能的影响[J].电镀与精饰,2006(03):11-14. |
| [3] | H.B. Suffredini;J.L. Cerne;F.C. Crnkovic .Recent developments in electrode materials for water electrolysis[J].International journal of hydrogen energy,2000(5):415-423. |
| [4] | Yamashita H;Yamamura T .The Relation Between Catalytic Ability for Hydrogen Evolution Reaction and Characteristics of Nickel-Tin Alloys[J].Journal of the Electrochemical Society,1993,140(8):2238-2243. |
| [5] | 常天义,张宝宏,丛文博,骆耀.Ni-Sn电极析氢性能研究[J].电化学,2002(03):343-347. |
| [6] | Qing Han;Kuiren Liu;Jianshe Chen;Xujun Wei .A study on the electrodeposited Ni-S alloys as hydrogen evolution reaction cathodes[J].International journal of hydrogen energy,2003(11):1207-1212. |
| [7] | 杜鑫,刘勇.控制电位脉冲电沉积法制备析氢Ni-S电极[J].电镀与精饰,2011(11):40-43. |
| [8] | 韩庆,陈建设,刘奎仁,李鑫,魏绪钧.电沉积非晶态Ni-S-Co合金在碱性介质中的析氢反应[J].金属学报,2004(03):331-336. |
| [9] | Arul Raj I;Vasu K I .Transition metal-based cathodes for hydrogen evolution in alkaline solution:electrocatalysis on nickel-based ternary electrolytic codeposits[J].Journal of Applied Electrochemistry,1992,22(5):471-476. |
| [10] | 付银辉,黎学明,杨文静,李武林,任晓虎.Ni-Mo-P活性阴极制备及析氢行为的研究[J].材料导报,2009(22):56-58. |
| [11] | 李克锋,王为,鞠峰,钱文鲲.电化学技术制备高效析氢电极[J].电镀与精饰,2004(01):27-30. |
| [12] | Emonts B;Hansen J B;Jrgensen S L .Compact methanol reformer test for fuel-cell powered light-duty vehicles[J].Journal of Power Sources,1998,71:288. |
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