采用单一组分铬酸盐钝化液处理化学镀Ni-P合金层获得一种超薄钝化膜.电化学测试表明,钝化处理显著提高了Ni-P合金层的耐蚀性.X-射线光电子能谱分析表明,钝化膜主要由O、Cr及Ni等元素组成,并根据Ar+离子对钝化膜的溅射速率估算出钝化膜δ约为6nm.Cr 2p精细X-射线光电子能谱谱图分析表明,钝化膜中Cr元素主要以Cr2O3和Cr(OH)3的形式存在.并对钝化膜成膜机理进行了简单探讨.
参考文献
| [1] | 廖西平,夏洪均.化学镀镍技术及其工业应用[J].重庆工商大学学报（自然科学版）,2009(04):399-402. |
| [2] | 贾韦,宣天鹏.化学镀镍在微电子领域的应用及发展前景[J].稀有金属快报,2007(03):1-6. |
| [3] | 吴其毅.电子元件表面化学镀镍的可焊性参数[J].电子工艺技术,1990(05):60-62. |
| [4] | 郭莉莉,孙莹.化学镀镍制品铬酸钝化与否的判断[J].中国表面工程,2007(02):30-32,36. |
| [5] | Directive 2002/95/EC of the European Parliament and the Council on the Restriction of the Use of Certain Hazardous Substances in Electrical and Electronic Equipments[J].Official Journal of the European Communities,2003 |
| [6] | 马静,胡建文,阎冬青,高青.Ni-P化学镀层钝化处理工艺研究[J].河北工业科技,2008(02):82-85. |
| [7] | Guojin Lu;Earl T. Ada;Giovanni Zangari .Investigations of the effect of chromate conversion coatings on the corrosion resistance of Ni-based alloys[J].Electrochimica Acta,2004(9/10):1461-1473. |
| [8] | 张轲,刘道新.FS-1化学镀Ni-P镀层的性能研究[J].腐蚀科学与防护技术,2002(06):346-348,358. |
| [9] | Long ZL.;Zhou YC.;Xiao L. .Characterization of black chromate conversion coating on the electrodeposited zinc-iron alloy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):123-136. |
| [10] | 邵海波,张鉴清,王建明,曹楚南.纯铝在强碱溶液中阳极溶解的电化学阻抗谱解析[J].物理化学学报,2003(04):372-375. |
| [11] | Guofeng Cui;Ning Li;Deyu Li et al.The physical and electrochemical properties of electroless deposited black nickel-phosphorus alloys[J].Surface and Coatings Technology,2006,200(24):6808-6814. |
| [12] | Zhang X;Sloof WG;Hovestad A;van Westing EPM;Terryn H;de Wit JHW .Characterization of chromate conversion coatings on zinc using XPS and SKPFM[J].Surface & Coatings Technology,2005(2/3):168-176. |
| [13] | Ramanauskas R.;Diaz-Ballote L.;Bartolo-Perez P. Quintana P.;Gudaviciute L. .Corrosion behaviour of chromated Zn and Zn alloy electrodeposits[J].Surface & Coatings Technology,2001(2):109-115. |
| [14] | Zhang X;van den Bos C;Sloof WG;Hovestad A;Terryn H;de Wit JHW .Comparison of the morphology and corrosion performance of Cr(VI)- and Cr(III)-based conversion coatings on zinc[J].Surface & Coatings Technology,2005(1):92-104. |
| [15] | Hughes AE;Taylor RJ;Hinton BRW .Chromate conversion coatings on 2024 Al alloy[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,1997(4):223-234. |
| [16] | Berger R;Bexell U;Grehk TM;Hornstrom SE .A comparative study of the corrosion protective properties of chromium and chromium free passivation methods[J].Surface & Coatings Technology,2007(2):391-397. |
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