综合介绍了线性电位扫描法、电位阶跃法、电子显微镜法和X-射线衍射等方法用于酸性氯化钾镀锌溶液中某些有机添加剂的作用机理的研究结果.认为作为载体光亮剂的聚氧乙烯醚表面活性剂对锌离子电化学还原的极化、镀锌层的晶粒大小和晶面取向及形貌、电结晶过程机理、成核速度常数、晶核的空间分布有最大的影响,获得镜面光亮的纳米锌镀层是聚氧乙烯醚与苄叉丙酮等的协同作用.
参考文献
| [1] | Kardos O;Foulke D G.Applications of mass transfer theory: Electrodeposition on small-scale profiles[A].Edited by C.W.Tobias.New York:John Wiley & Sons,Ins,1962:154. |
| [2] | Kardos O .Current distribution on microprofiles Part Ⅰ,Ⅱ,Ⅲ[J].Plating,1974,61(129):229,316. |
| [3] | Madore C;Matlose M;Landolt D .Blocking inhibitors in cathodic leveling Ⅰ[J].Journal of the Electrochemical Society,1996,143(12):3927. |
| [4] | Madore C;Landolt D .Blocking inhibitors in cathodic leveling Ⅱ[J].Journal of the Electrochemical Society,1996,143(12):3936. |
| [5] | Amllard J;Epelboin I;Froment M et al.Inhibition and nickel electrocrystallization[J].Journal of Applied Electrochemistry,1979,9:233. |
| [6] | Lec D N;Ye G C .Orientation and microstructure of watts and bright nickel electrodeposite[J].Plating and Surface Finishing,1981,68(11):47. |
| [7] | Choi H J;Weil R .Variation of the structure of nickel electrodeposits[J].Plating and Surface Finishing,1981,68(05):110. |
| [8] | Weil R;Stanko G J;Moser D E .The formation of three dimensional, epitaxial crystallites during the electrocrystallization of nickel and their role in crystal-defect development[J].Plating and Surface Finishing,1976,63(09):34. |
| [9] | Oniciu L;Muresan L .Some fundamental aspects of leveling and brightening in metal electrodeposition[J].Journal of Applied Electrochemistry,1991,21:565. |
| [10] | 查全性.电极过程动力学导论(第3版)[M].北京:科学出版社,2002:153,298,313. |
| [11] | 陈永言.电化学基础[M].天津:天津科学技术出版社,1999:135,149,171,179. |
| [12] | 周昭民.金属电沉积-原理和方法[M].上海:上海科学技术出版社,1987:178,288-305,373,380,386. |
| [13] | 陈文亮;邹津耘;黄国英 等.酸性光亮镀铜电解液中添加剂的整平作用研究[J].武汉大学学报(理学版),1980,26(03):23. |
| [14] | 吴辉煌;许书楷;周绍民 .锌在玻碳上电化学成核机理[J].物理化学学报,1985,1(04):357. |
| [15] | 郑筱梅.镀镍添加剂结构与平滑能力的相关性研究[J].材料保护,2000(03):3-5. |
| [16] | 鞠传伟.关于镀镍光亮剂分子结构的探讨[J].电镀与环保,2001(03):16-17. |
| [17] | 舒余德;张昭 .电镀添加剂作用机理的发展概况[J].电镀与环保,1999,19(06):5. |
| [18] | 储荣邦;沈品华;董愚.氯化钾镀锌[M].上海:上海科学技术出版社,1991:213. |
| [19] | 邹群,黄清安.氯化物微酸性光亮镀锌的研究现状[J].材料保护,2001(05):15-17. |
| [20] | 陈永言,黄清安.电位扫描法研究氯化钾镀锌添加剂[J].材料保护,1995(09):1. |
| [21] | 陈永言.氯化钾镀锌添加剂作用机理的研究[J].材料保护,1996(05):7. |
| [22] | 洪春;邝少林.宽温度无铵氯化物光亮镀锌的研究[A].长沙:湖南大学出版社,1986:4. |
| [23] | 黄全安;周运鸿;查全性 .聚氧乙烯表面活性物质在电极表面的吸附规律[J].材料保护,1965,5(03):15. |
| [24] | 陈永言;喻敬贤;张红 等.添加剂对氯化钾溶液中锌镀层的形貌和织构的影响[J].武汉大学学报(自然科学版),1998,44(02):183. |
| [25] | Yu Jingxian;Yang Hanxi;Huang Qing'an;Chen Yongyan .Influences of organic additives on zinc electrocrystallization from KCl solutions[J].Journal of the Electrochemical Society,1999(5):1789-1793. |
| [26] | 喻敬贤,陈永言,黄清安,杨汉西.纳米光亮镀锌层的结构研究[J].高等学校化学学报,1999(01):107. |
| [27] | 荆天辅,乔桂英,熊毅,邵光杰,于升学,张纯江,侯登振.添加剂对喷射电沉积纳米晶镍的影响[J].材料保护,2001(07):16-17. |
| [28] | S.C.Kou;A.Hung .Studies of Acid Sulfate Copper Pulse Reversal Current Electrodeposition[J].Plating & Surface Finishing,2000(5):140-144. |
| [29] | 南安普顿大学电化学组;柳厚田;徐品弟.电化学中的仪器方法[M].上海:复旦大学出版社,1992:295. |
| [30] | Scharifker B R;Hills G J .Theortical and exeperimental studies of multiple nucleation[J].Electrochimica Acta,1983,28:879. |
| [31] | 张启富,涂抚洲.非晶态镍磷合金电沉积机理的研究[J].电镀与涂饰,2001(01):1-6,11. |
| [32] | 王先友.三价铬溶液电结晶机理研究[C].论文集,1998:21-23. |
| [33] | 喻敬贤;陈永言;黄清安 .某些添加剂对锌在玻碳电极上电结晶过程的影响[J].武汉大学学报(理学版),1996,42(06):686. |
| [34] | Scharifker B R;Mostany J .Three-dimensional nucleation with diffusion growth[J].Journal of Electroanalytical Chemistry,1984,177:13. |
| [35] | 喻敬贤,曹宏庆,陈永言,杨汉西,康立山.添加剂对锌电结晶行为的影响及参数的演化优化[J].化学学报,1999(09):953-960. |
| [36] | Jingxian Yu;hongqing Cao;Yongyan Chen;Lishan King;Hanxi Yang .A new approach to the estimation of electrocrystallization parameters[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,1999(1):69-73. |
| [37] | Heerman L;Tarallo D .Electrochemical nucleation in microelectrodes, theory and experiment for diffusion controlled growth[J].Journal of Electroanalytical Chemistry,1998,451:101. |
| [38] | Scharifker B R;Mostany J;Serruya A .On the spatial distribution of nuclei on electrode surfaces[J].Electrochimica Acta,1992,37:2503. |
| [39] | Scharifker B R;Mostany J;Serruya A .Spatial distribution of electrodeposited lead nuclei on to ritreous carbon beyond their nearest neighbours[J].Journal of Electroanalytical Chemistry,1995,383:37. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%