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采用等离子喷涂方法在304不锈钢表面制备了TiO_2、AT40(40%TiO_2,60%Al_2O_3)涂层,研究了涂层对甲基橙的光催化降解性能.采用金相分析方法和扫描电镜(SEM)观察了涂层微观结构,用X射线衍射法分析了涂层的相结构.结果表明:涂层与基体结合紧密,表面的孔隙有利于降解率的提高,锐钛型TiO_2的含量是影响光催化效果的关键,纯TiO_2涂层的降解率高于AT40涂层.

TiO_2 and AT40(40%TiO_2:60% Al_2O_3)coatings on 304 stainless steel were prepared by plasma spra-ying in order to study the properties of photo-catalytic degradation of methyl-orange. The micro-structure of the as-sprayed coatings was characterized by metallographic analysis and SEM. X-ray diffraction was used to evaluate the phase structure of the coatings. The results show that the combination of the coatings is very tightness. The porosity is propitious to im-prove the photo-catalytic property. The content of rutile TiO_2 is the key factor for the Photo-catalysis. The degradation rate of the pure TiO_2 coating is better than the AT40 coating.

参考文献

[1] 杨洪伟,栾伟玲,涂善东.等离子喷涂技术的新进展[J].表面技术,2005(06):7-10.
[2] 冯拉俊,刘兵.等离子喷涂制备TiO2纳米颗粒[J].中国表面工程,2004(02):11-14,17.
[3] 顾德恩,杨邦朝,胡永达.非金属元素掺杂TiO2的可见光催化活性研究进展[J].功能材料,2008(01):1-5.
[4] 张玉叶,吴文贤,李强,陈进武,吴敏生.等离子喷涂纳米结构AT13基涂层工艺图的建立[J].表面技术,2008(02):64-66,80.
[5] 李亚峰,赵艳红,陈平,赵洁,刘娟,林强.负载型TiO2光催化剂的制备及光催化活性研究[J].沈阳建筑大学学报(自然科学版),2008(01):123-128.
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