综述了Ni-MH电池负极材料贮氢合金的表面处理方法.包括它们对合金电极(或Ni-MH电池)性能的影响、作用机理及其操作工艺.
参考文献
| [1] | Hu WK.;Noreus D.;Ye Z. .Studies on multi-component rare earth-based hydrogen storage alloys with small amounts of boron[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):314-320. |
| [2] | 陈卫祥 .MH电极表面化学还原处理正交实验[J].电源技术,1998,22(05):198. |
| [3] | 陈卫祥;陈昀;潘洪革 等.贮氢合金表面处理改善Ni/MH电池1C充放电性能[J].物理化学学报,1998,14(08):742. |
| [4] | 潘洪革;陈昀;陈长聘 等.用含KBH4碱液处理改善MlNi3.7Co0.6Mn0.4Al0.3贮氢合金电极的动力学性能[J].金属学报,1999,35(03):300. |
| [5] | Nobuhiro kuriyama;Tstsuo sakai;Hiroshi miyamura et al.Electrochemical activity enhancement of a LaNi4.7 Al0.3electrode treated with an alkaline solution containing H2O2[J].Journal of Alloys and Compounds,1997,253-254:598-600. |
| [6] | M.Ikoma;K.Komori .Effect of alkali-treatment of hydrogen storage alloy on the degradation of Ni/MH batteries[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):92-98. |
| [7] | Weon-Kyung Choi;Katsuhiro Yamataka;Shu Guo Zhang;Hiroshi Inoue;Chiaki Iwakura .Effects of surface treatment with boiling alkaline solution on electrochemical and physicochemical properties of the Zr{sub}0.9Ti{sub}0.1Ni{sub}1.1Co{sub}0.1Mn{sub}0.6V{sub}0.2 alloy electrode[J].Journal of the Electrochemical Society,1999(1):46-48. |
| [8] | Deyi Yan;Suda S .Electrochemical characteristics of LaNi4.7Al0.3 alloy activated by alkaline solution containing hydrazine[J].Journal of Alloys and Compounds,1995,223:28-31. |
| [9] | Jung JH.;Lee JY.;Liu BH. .Activation behavior of Zr0.7Ti0.3Cr0.3Mn0.3V0.4Ni alloy electrode modified by the hot-charging treatment[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):306-310. |
| [10] | Andreas Zuttel;Felix Meli .Louis schlapbach.Effects of pretreatment on the activation behavior of Zr (V0.25Ni0.75)2 metal hydride electrodes in aikaline solution[J].Journal of Alloys and Compounds,1998,280:314-320. |
| [11] | Chen J;Bradhurst D H;Dou S X et al.Surface and electrode properties of Zr(V0.25Ni0.75)2 alloy treated with ultrasound-solution[J].Journal of Alloys and Compounds,1994,209:99-105. |
| [12] | Liu F J;Ota H;Okamoto S et al.Surface properties of the fluorinated La-incorporated Ti/Zr-based AB2 laves phase alloys[J].Journal of Alloys and Compounds,1997,253-254:452-458. |
| [13] | 吴勋;杨勇;尤金跨.氟出理对AB5型金属氢化物电极性能影响[A].新乡,1998:235. |
| [14] | Gao Xueping;Deying Song;Yunshi Zhang et al.Electrochemical and surface properties of the Zr (V0.2Mn0.2Ni0.6 ) 2.4 alloy electrode[J].Journal of Alloys and Compounds,1995,229:268-273. |
| [15] | Sun Y M;Iwata K;Chiba S et al.Studies on the properties and characteristics of the fluorinated AB5 hydrogenabsorbing electrode alloys[J].Journal of Alloys and Compounds,1997,253-254:520-524. |
| [16] | Sakashita M;Li Z P;Suda S .Fluorination mechanism and its effects on the electrochemical properties of metal hydrides[J].Journal of Alloys and Compounds,1997,253-254:500-505. |
| [17] | T.Imoto;K.Kato .Influence of surface treatment by HCl aqueous solution on electrochemical characteristics of a Mm(Ni-Co-Al-Mn)4.76 alloy for nickel-metal hydride batteries[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):274-278. |
| [18] | 熊义辉;沈建荣;林根文 等.用电镀方法在贮氢合金粉末表面包覆铜的探索[J].电源技术,1997,21(03):11. |
| [19] | 宏存茂;杨敬武;杨勇 等.AB5型球型合金粉的表面处理研究[J].物理化学学报,1998,14(02):154. |
| [20] | 张大为;袁华堂;汪根时 等.关于贮氢合金表面包铜工艺的几个问题[J].电源技术,1998,22(03):1. |
| [21] | Jae-Han Jung;Han-Ho Lee;Dong-Myung Kim et al.Degradation behavior of Cu-coated Ti-Zr-Mn-Ni metal hydride electrodes[J].Journal of Alloys and Compounds,1998,266:266-270. |
| [22] | Wang CY;Bradhurst DH;Liu HK;Dou SX;Yao P .Surface modification of Mg sub 2 Ni alloy in an acid solution of copper sulfate and sulfuric acid[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):267-271. |
| [23] | 南俊民;杨勇;林祖赓 等.铜包覆AB5型金属氢化物电极的电化学性能研究[J].电源技术,1998,22(05):188. |
| [24] | 孙俊才.表面包覆贮氢合金电极的电化学特性[J].稀土,1994(05):5. |
| [25] | Luo JL.;Cui N. .Effects of microencapsulation on the electrode behavior of Mg2Ni-based hydrogen storage alloy in alkaline solution[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):299-305. |
| [26] | Chen J.;Dou SX.;Liu HK.;Bradhurst DH. .The effect of chemical coating with Ni on the electrode properties of Mg2Ni alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):290-293. |
| [27] | A. Visintin;C. A. Tori;G. Garaventta;W. E. Triaca .The electrochemical performance of pd-coated metal hydride electrodes with different binding additives in alkaline solution[J].Journal of the Electrochemical Society,1998(12):4169-4172. |
| [28] | B. S. Haran;B. N. Popov;R. E. White .Studies on electroless cobalt coatings for microencapsulation of hydrogen storage alloys[J].Journal of the Electrochemical Society,1998(9):3000-3007. |
| [29] | 陈卫祥,唐致远,陈长聘.贮氢合金表面分析和金属氢化物电极电催化活性[J].化学学报,1998(06):564-569. |
| [30] | Chiaki Iwakura;Weon-Kyung Choi;Shu Guo Zhang;Hiroshi Inoue .Mechanism of hydrogen absorption in Zr{sub}0.9Ti{sub}0.1Ni{sub}1.1Co{sub}0.1Mn{sub}0.6V{sub}0.2 alloy during alkali treatment with a boiling 6 M KOH solution[J].Electrochimica Acta,1999(10):1677-1679. |
| [31] | Haru-Hisa Uchida;Kumi Moriaii;Kazuki Aoyama et al.Effect of alkaline pretreament on the initial activation of LaNi5 and LaNi2.5Co2.5 in the H2 gas and electrochemical reactions[J].Journal of Alloys and Compounds,1997,253-254:525-528. |
| [32] | Tetsuo Sakai;Hiroshi Ishikawa;Keisuke Oguro et al.Effects of microencapsulation of hydrogen storage alloy on the performances of sealed nickel/metal hydride batteries[J].Journal of the Electrochemical Society,1987,134(03):558. |
| [33] | 陈启元,王志兴,李新海,郭炳昆,刘建华.贮氢合金La（NiSnCo）5.12微包覆镍研究[J].中国有色金属学报,1998(03):477-481. |
| [34] | Deyi Yan;Gary Sandrock;Seijirau Suda .Activation of Zr0.5Ti0.5V0.75Ni0.25 alloy electrodes by hot alkaline solutions[J].Journal of Alloys and Compounds,1994,216:237-242. |
| [35] | Masao Matsuoka;Kazuaki Asai;Yukio Fukumoto et al.Surface modification of hydrogen storage alloy electrode with an alkaline solution containing potassium borohydride as a reducing agent[J].Electrochimica Acta,1993,38(05):659. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%