绘制了单烷基磷酸酯(MAP)-乙醇-水三元体系在30℃的相图,用电导法结合偏光显微镜等测试仪器将相图分为W/O微乳区、O/W微乳区、MAP过量区、微乳液与液晶共存区和液晶单相区.选取相图中W/O微乳区内的一个液相组分点,制备了纳米羟基磷灰石.小角X射线衍射、透射电子显微镜分析结果显示:纳米羟基磷灰石具有规则排列的层状微观结构.
参考文献
| [1] | Cao L Y;Zhang C B;Huang J F .Synthesis of hydroxyapatite nanoparticles in ultrasonic precipitation[J].Ceramics International,2005,31:1041-1044. |
| [2] | Ota Y.;Kasuga T.;Abe Y.;Iwashita T. .Novel preparation method of hydroxyapatite fibers[J].Journal of the American Ceramic Society,1998(6):1665-1668. |
| [3] | Liou SC;Chen SY;Liu DM .Synthesis and characterization of needlelike apatitic nanocomposite with controlled aspect ratios.[J].Biomaterials,2003(22):3981-3988. |
| [4] | T. Anee Kuriakose;S. Narayana Kalkura;M. Palanichamy;D. Arivuoli;Karsten Dierks;G. Bocelli;C. Betzel .Synthesis of stoichiometric nano crystalline hydroxyapatite by ethanol-based sol-gel technique at low temperature[J].Journal of Crystal Growth,2004(1/4):517-523. |
| [5] | F. Zhang;Z.-H. Zhou;S.-P. Yang .Hydrothermal synthesis of hydroxyapatite nanorods in the presence of anionic starburst dendrimer[J].Materials Letters,2005(11):1422-1425. |
| [6] | Kun Wei;Yingjun Wang;Chen Lai .Synthesis and characterization of hydroxyapatite nanobelts and nanoparticles[J].Materials Letters,2005(2/3):220-225. |
| [7] | Bose S.;Saha SK. .Synthesis and characterization of hydroxyapatite nanopowders by emulsion technique[J].Chemistry of Materials,2003(23):4464-4469. |
| [8] | Lim G K;Wang J;Ng S C .Formation of nanocrystalline hydroxyapatite in nonionic surfactant emulsions[J].Langmuir,1999,15(22):7472-7477. |
| [9] | Sonoda K.;Furuzono T.;Walsh D.;Sato K.;Tanaka J. .Influence of emulsion on crystal growth of hydroxyapatite[J].Solid state ionics,2002(1/4):321-327. |
| [10] | R.Hofer;M.Textor;N.D.Spencer .Alkyl Phosphate Monolayers,Self-Assembled from Aqueous Solution onto Metal Oxide Surfaces[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(13):4014-4020. |
| [11] | 韦亚兵,吴静,吴石山,郑昌仁.O/W型微乳液法制备PMMA纳米粒子的研究--（Ⅰ）相图,增容效应,反应动力学[J].高分子材料科学与工程,2005(01):141-144. |
| [12] | Francesca Porta;Concetta Bifulco;Paola Fermo;Claudia L. Bianchi;Michaela Fadoni;Laura Prati .Synthesis of spherical nanoparticles of Cu_2L_2O_5 (L = Ho, Er) from W/O microemulsions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,1999(3):281-290. |
| [13] | Duan G R;Yang X J;Huang G H .Water/span80/triton X-100/n-hexyl alcohol/n-octane microemulsion systemand the study of its application for preparing nanosized zirconia[J].Materials Letters,2006,60:1582-1587. |
| [14] | 花王公司 .洗净剂组成物[P].JP 641579,1994-02-15. |
| [15] | 花王公司 .酸性头发处理剂组成物[P].JP 6329521,1994-11-29. |
| [16] | 崔正刚;殷福珊.微乳化技术及应用[M].北京:中国轻工业出版社,1999:79-80. |
| [17] | 赵国玺;朱埗瑶.表面活性剂原理[M].北京:中国轻工业出版社,2003:299-300. |
| [18] | 罗静卿,赵新华,周固.CTAB/正丁醇-正辛烷-水和盐水的拟三元体系相图及微乳液微观结构的电导研究[J].高等学校化学学报,2004(06):1085-1089. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%