镁及其合金的铸造、熔炼需要在SF6的保护气氛中进行,目前对其研究还不完善.为此,用SEM,TEM和XRD研究了熔态AZ91D镁合金在空气/SF6保护气氛中形成的表面膜特征.结果表明:保护性表面膜分为两层,最外层主要为疏松多晶的MgO及含有少量Al的氧化物和微量的氟化物;内层为结晶MgF2;随着AZ91D在保护气氛中暴露时间的增加,表面膜中F/O原子比显著增加,表面粗糙度增加;表面膜超过一定厚度后,主要为F和Mg发生反应;表面膜表面弥散着大小不一的白色片状物,其主要成分为MgO,内含少量MgF2.部分近表面区域断面中有不连续的白亮富F(原子分数约为70%)小半圆区域,富F的小半圆亮区之间F含量显著降低;部分为一条厚度不均匀的白亮带,其中F原子分数也很不均匀.富F区中F/Mg原子比显著大于MgF2中的2/1,F可能通过富F区域不断从保护气氛向AZ91D镁合金内部扩散形成MgF2.
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