采用化学法合成了乱层石墨结构B-C-N化合物,在不同温度下进行高温处理后,经X射线衍射(XRD)、透射电子显微镜(TEM)、高分辨电子显微镜(HREM)和X射线能谱(EDX)对合成产物的结构、晶体学参数、成分等进行分析.结果表明,处理温度对乱层石墨结构B-C-N化合物的晶化有较大影响.随处理温度增加,B-C-N化合物由乱层石墨结构向多晶体转变.1600℃处理后可以得到纯六方B-C-N多晶固溶体,晶格参数为a=0.251 mm,c=0.666 mm.EDX测定出晶化后B-C-N化合物的成分为B0.41C0.09N0.50.
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