区别于改良西门子法、硅烷法、碳热还原法、区域熔炼法等多晶硅生产工艺,利用等离子体技术,建立了以硅的氯化物为原料,一步法制备多晶硅的实验装置和工艺流程,并在此基础上进行了粒状多晶硅制备的实验.实验表明,SiCl4单程转化率超过70%,多晶硅选择性60%.利用XRD、SEM、AS等分析手段,对所得产物进行了表征.与纯度为7个9的多晶硅标样的比较表明,实验产物达到了太阳能级.此方法为多晶硅生产极大地放宽了原料选择条件,为低成本生产太阳能级多晶硅提供了一种新的途径.
参考文献
[1] | 梁骏吾.电子级多晶硅的生产工艺[J].中国工程科学,2000(12):34-39. |
[2] | 汤传斌.粒状多晶硅生产概况[J].有色冶炼,2001(03):29-31,42. |
[3] | White, CM;Ege, P;Ydstie, BE .Size distribution modeling for fluidized bed solar-grade silicon production[J].Powder Technology,2006(1/2):51-58. |
[4] | A. Mueller;M. Ghosh;R. Sonnenschein;P. Woditsch .Silicon for photovoltaic applications[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2006(2/3):257-262. |
[5] | 2006年全球及中国太阳能多晶硅产业链研究报告摘要[R/OL].http://www.okokok.com.cn/Sh-op/Class9/200610/11111.html |
[6] | Woditsch P.;Koch W. .Solar grade silicon feedstock supply for PV industry[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1/4):11-26. |
[7] | 于站良,马文会,戴永年,杨斌,魏奎先.太阳能级硅制备新工艺研究进展[J].轻金属,2006(03):43-47. |
[8] | K.B. Tynyshtykbaev;K.T. Igibaev;D.K. Suleev .Direct carbothermal receiving of solar grade silicon[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2006(2/3):296-302. |
[9] | 全球半导体技术的最新进展[J].电子产品世界,2001(03):51-52. |
[10] | N.Yuge;M. Abe;K. Hanazawa .Purification of Metallurgical-Grade Silicon up to Solar Grade[J].Progress in photovoltaics,2001(3):203-209. |
[11] | De Wolf S.;Szlufcik J.;Delannoy Y.;Perichaud I.;Hassler C.;Einhaus R. .Solar cells from upgraded metallurgical grade (UMG) and plasma-purified UMG multi-crystalline silicon substrates[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1/4):49-58. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%