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区别于改良西门子法、硅烷法、碳热还原法、区域熔炼法等多晶硅生产工艺,利用等离子体技术,建立了以硅的氯化物为原料,一步法制备多晶硅的实验装置和工艺流程,并在此基础上进行了粒状多晶硅制备的实验.实验表明,SiCl4单程转化率超过70%,多晶硅选择性60%.利用XRD、SEM、AS等分析手段,对所得产物进行了表征.与纯度为7个9的多晶硅标样的比较表明,实验产物达到了太阳能级.此方法为多晶硅生产极大地放宽了原料选择条件,为低成本生产太阳能级多晶硅提供了一种新的途径.

参考文献

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[3] White, CM;Ege, P;Ydstie, BE .Size distribution modeling for fluidized bed solar-grade silicon production[J].Powder Technology,2006(1/2):51-58.
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[5] 2006年全球及中国太阳能多晶硅产业链研究报告摘要[R/OL].http://www.okokok.com.cn/Sh-op/Class9/200610/11111.html
[6] Woditsch P.;Koch W. .Solar grade silicon feedstock supply for PV industry[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1/4):11-26.
[7] 于站良,马文会,戴永年,杨斌,魏奎先.太阳能级硅制备新工艺研究进展[J].轻金属,2006(03):43-47.
[8] K.B. Tynyshtykbaev;K.T. Igibaev;D.K. Suleev .Direct carbothermal receiving of solar grade silicon[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2006(2/3):296-302.
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[10] N.Yuge;M. Abe;K. Hanazawa .Purification of Metallurgical-Grade Silicon up to Solar Grade[J].Progress in photovoltaics,2001(3):203-209.
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