对水热合成的V-P-O-en体系中七种常见不同结构钒磷酸盐的热稳定性进行了TG-DTA、FT-IR和XRD的比较研究.化合物中有机分子的受热脱除是阶段性的,吸放热效应与化合物中有机分子的含量有关.影响热稳定性的因素有:无机骨架类型、骨架强度以及骨架与有机模板分子作用强度.无机骨架自身强度较低是导致这类化合物热稳定性低的根本原因.
参考文献
[1] | Cheetham A K;Ferey G;Loiseau T .Open-framework Inorganic Materials[J].Angewandte Chemie International Edition,1999,38:3268. |
[2] | Taulelle F .Crystallogenesis of Microporous Metallophosphates[J].Current Opinion in Solid State and Materials Science,2001,5:407. |
[3] | Harrison W T A .Templated Inorganic Networks:Recent Developments[J].Current Opinion in Solid State and Materials Science,2002,6:407. |
[4] | Ferey G .Microporous Solids:from Organically Templated Inorganic Skeletons to Hybrid Frameworks Ecumenism in Chemistry[J].CHEMISTRY OF MATERIALS,2001,13:3084. |
[5] | Amoros P;Dolores M;Beltran A et al.New Trends in V-P-O Solids[J].Current Opinion in Solid State and Materials Science,1999,4:123. |
[6] | Hagrman P J;Finn R C;Zubieta J .Molecular Manipulation of Solid State Structure:Influences of Organic Components on Vanadium Oxide Architectures[J].Solid State Sciences,2001,3:745. |
[7] | 王永在 .钒磷酸盐的水热合成、结构表征及热稳定性研究[D].中国地质大学(北京),2005. |
[8] | 杨赞中,廖立兵,杜洪兵.新型磷酸钒孔道结构化合物(H3NCH2CH2NH3)3[(VO)4(PO4)2(HPO4)4]的表征及热性能研究[J].人工晶体学报,2002(02):148-152. |
[9] | Zhang Y;Warren C J;Clearfield A et al.Hydrothermal Synthesis and Crystal Structure of (NH3CH2CH2NH3)[V (OH) (HPO4)2].H2O with Novel 1-D {V3+-OH-V3+} Polymeric Chains[J].Polyhedron,1998,17:2575. |
[10] | Zima V.;Lii KH. .Synthesis and crystal structures of (NH3CH2CH2NH3)(1.5) [(VO)(2)(HPO4)(2)(PO4)] and (C4H12N2)(2)[V4O6H(HPO4)(2)(PO4)(2)], two layered vanadium phosphates templated with organic diamines[J].International Journal of Quantum Chemistry,2003(2):424-430. |
[11] | 杜洪兵,廖立兵,杨赞中,马哲生,熊明.新型磷酸钒孔道结构化合物(H3NCH2CH2NH3)3-[(VO)4(PO4)2(HPO4)4]的水热合成及结构表征[J].化学学报,2001(02):274-278. |
[12] | Harrison W T A;Hsu K;Jacobson A J .Hydrothermal Synthesis and Structural Characterization of an Organically Templated Open-framework Vanadium Phosphate:[(VO)2(PO4)2(H2PO4)].N2C2H10,a New Three-dimensional,Organically Templated Mixed-valence Vanadium Phosphate Related to the 2VOSO4 H2SO4Structure[J].Chemistry of Materials,1995,7:2004. |
[13] | Zhang Y P;Clearfield A;Haushalter R C .Hydrothermal Synthesis and Crystal Structure of an Organically Templated Open-framework Vanadium Phosphate:(NH3(CH2)2NH3)4[VⅢ(H2O)2(VⅣO)6(OH)2(PO4)5(HPO4)3].3H2O[J].Chemistry of Materials,1995,7:1221. |
[14] | Soghomonian V;Chen Q;Haushalter R C et al.Vanadium Phosphate Framework Solid Construted of Octahedra,Square Pyramids,and Tetrahedral with a Cavity Diameter of 18.4[J].Angewandte Chemie International Edition,1993,32:610. |
[15] | 王永在,廖立兵,李国武,熊明.钒磷酸盐(NH3CH2CH2NH2)[VOPO4]的水热合成和结构表征[J].化学学报,2005(01):75-80. |
[16] | Meyer L M;Haushalter R C;Zubieta J .The First Aluminophosphates:Hydrothermal Synthesis and Structure of Cs[(VO)Al(PO4)2].H2O,Rb[(VO)Al(PO4)2].H2O,(NH3CH2CH2NH2)[(VO)Al(PO4)2],and CH3NH3[(VO)Al(PO4)2][J].Journal of Solid State Chemistry,1996,125:200. |
[17] | 王永在,廖立兵.孔道结构钒铝磷酸盐(NH3CH2CH2NH2)[(VO)Al(PO4)2]的水热合成及热稳定性[J].人工晶体学报,2005(01):84-88. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%