在综述Pb(Zr,Ti)O3(PZT)基反铁电材料的研制与性能研究进展的基础上,重点探讨了PZT95/5反铁电材料和在PZT基础上掺杂改性的Pb(Zr,Sn,Ti)O3(PZST),(Pb,La)(Zr,Sn,Ti)O3 (PLZST)反铁电材料.总结了利用La3+、Nb4+、Hf4+、Sr2+、Ba2+和Nd3+等离子对富锆PZT以及PZST粉体、陶瓷以及薄膜材料的掺杂取代改性研究.讨论了各类PZT基反铁电材料的铁电(FE)-反铁电(AFE)相变机理以及其场致应变性能.展望了PZT基反铁电材料今后研究与应用的发展方向.
参考文献
| [1] | Kittel C .Theory of Antiferroelectric Crystals[J].Physical Review,1951,82:729-732. |
| [2] | Sawaguchi E .Ferroelectricity Versus Antiferroelectricity in the Solid Solutions of PbZrO3 and PbTiO3[J].Journal of The Physical Society of Japan,1953,8:615. |
| [3] | Berlincourt D;Jaffe H;Krueger H H A et al.Release of Electric Energy in PbNb(Zr,Ti,Sn)O3 by Temperature and by Pressure-enforced Phase Transitions[J].Applied Physics Letters,1963,3:90-92. |
| [4] | Berlincourt D;Krueger H H A .Domain Processes in Lead Titanate Zirconate and Barium Titanate Ceramics[J].Journal of Applied Physics,1959,30:1804-1810. |
| [5] | 高西汉 .钙钛矿结构[J].压电与声光,1994,16:44-48. |
| [6] | Shirane G .Suzuki K.Crystal Structure of Pb (Zr,Sn)O3[J].Journal of The Physical Society of Japan,1952,7:333-338. |
| [7] | 董显林;孙大志;王永令 .PZT基陶瓷铁电-反铁电相界处各向异性的研究[J].无机材料学报,1995,10(02):193-198. |
| [8] | Wang Y L;Chen Z M;Sun Y R et al.Phase Transition Study of PZT95/5 Ceramics[J].Physica B+C,1988,150(1-2):168-174. |
| [9] | Viehland D.;Dai XH.;Xu Z.;Li JF. .STRUCTURAL AND PROPERTY STUDIES OF HIGH ZR-CONTENT LEAD ZIRCONATE TITANATE[J].The journal of physics and chemistry of solids,1996(10):1545-1554. |
| [10] | Gonnard P;Troccaz M .Evaluation of the Valency of Fe,Cr,Cu,Sb Doping Ions in Pb(Zr0.95Ti0.05)O3 Ceramics[J].Journal of Solid State Chemistry,1983,47:92-97. |
| [11] | Fritz I J;Keck J D .Pressure-temperature Phase Diagram for Several Modified Lead Zirconate Ceramics[J].Journal of Physics and Chemistry of Solids,1978,39:1163. |
| [12] | Haertling G H;Land C E .Hot Pressed (Pb,La)(Zr,Ti)O3 Ferroelectric Electrooptic Applications[J].Journal of the American Ceramic Society,1971,54:1-11. |
| [13] | Dai X H;Dwight Viehland .Effects of Lanthanum Modification on the Antiferroelectric-Ferroelectric Stability of High Zirconium-content Lead Zirconate Titanate[J].Journal of Applied Physics,1994,76(06):3701-3709. |
| [14] | Ill Won Kim;Dae Su Lee;Sun Hee Kang;Chang Won Ahn .Antiferroelectric characteristics and low frequency dielectric dispersion of Pb_(0.175)La_(0.025)(Zr_(0.95)Ti_(0.05))O_3 thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(1/2):115-120. |
| [15] | Yongjian Yu;Raj N. Singh .Effect of composition and temperature on field-induced properties in the lead strontium zirconate titanate system[J].Journal of Applied Physics,2000(12):7249-7257. |
| [16] | Elharrad I.;Carabatosnedelec C.;Handerek J.;Ujma Z.;Dmytrow D.;Becker P. .RAMAN INVESTIGATION OF UNDOPED, NIOBIUM-DOPED, AND LANTHANUM-DOPED LEAD ZIRCONATE-TITANATE CERAMICS[J].Journal of Applied Physics,1995(9):5581-5591. |
| [17] | C.Heremans;H.L.Tuller .Lead hafnate zirconate titanate-based perovskite materials for actuation[J].Journal of the European Ceramic Society,1999(6/7):1133-1137. |
| [18] | Robert E. Setchell .Shock wave compression of the ferroelectric ceramic Pb_(0.99)(Zr_(0.95)Ti_(0.05))_(0.98)Nb_(0.02)O_(3): Depoling currents[J].Journal of Applied Physics,2005(1):122-137. |
| [19] | 刘高旻,谭华,袁万宗,王海晏,张毅.冲击加载下PZT-95/5陶瓷铁电-反铁电相变实验研究[J].高压物理学报,2002(03):231-236. |
| [20] | Chen A;Zhi Y .Dielectric Behavior of PbZr0.52Ti0.48O3 Thin Films:Intrinsic and Extrinsic Dielectric Responses[J].Applied Physics Letters,2004,85(17):3821-3823. |
| [21] | Wang QM;Ding YP;Chen QM;Zhao MH;Cheng JR .Crystalline orientation dependence of nanomechanical properties of Pb(Zr0.52Ti0.48)O-3 thin films[J].Applied physics letters,2005(16):2903-1-2903-3-0. |
| [22] | Xu BM.;Bernstein JJ.;Cross LE. .Ferroelectric and antiferroelectric films for microelectromechanical systems applications[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2000(0):712-718. |
| [23] | Raynald Seveno;Hartmut W. Gundel;Dominique Averty .Pulse characterization of antiferroelectric PbZrTiO_3 thin films[J].Journal of the European Ceramic Society,2005(12):2263-2267. |
| [24] | Yingbang Yao;S. G. Lu;Haydn Chen;Jiwei Zhai;K. H. Wong .Role of oxygen pressure during pulsed laser deposition on the electrical and dielectric properties of antiferroelectric Ianthanum-doped lead zirconate stannate titanate thin films[J].Journal of Applied Physics,2004(1):569-574. |
| [25] | Seveno R;Gundel H W;Seifert S .Preparation of Antiferroelectric PbZr xTi1-xO3 thin films on LaSrMnO3-coated Steel Substrates[J].Applied Physics Letters,2001,79(25):4204-4206. |
| [26] | Xu B M;Ye Y H;Wang Q M et al.Dependence of Electrical Properties on Film Thickness in Lanthanum-doped Lead Zirconate Titanate Stannate Antiferroelectric Thin Films[J].Journal of Applied Physics,1999,85(07):3753-3758. |
| [27] | Menguy, N.;Caranoni, C.;Hilczer, B.;Roleder, K.;Dec, J. .Transmission electron microscopy studies of Pb(Zr_(0.99)Ti_(0.01))O_3 single crystals[J].The journal of physics and chemistry of solids,1999(5):625-629. |
| [28] | Viehland D. .TRANSMISSION ELECTRON MICROSCOPY STUDY OF HIGH-ZR-CONTENT LEAD ZIRCONATE TITANATE[J].Physical Review.B.Condensed Matter,1995(2):778-791. |
| [29] | 冯玉军 .Pb（Zr，Sn，Ti）O<,3>反铁电材料的性能和制备[D].西安交通大学,2001. |
| [30] | 陈铭 .Pb(Zr，Sn，Ti)O<,3>反铁电陶瓷的制备及其电致应变性能应用研究[D].同济大学,2001. |
| [31] | Viehland D;Forst D;Xu Z et al.Incommensurately Modulated Polar Structure in Antiferroelectric Sn-modifed Lead Zirconate Titanate:the Modulated Structure and Its Influence on Electrically Induced Polarizations and Strains[J].Journal of the American Ceramic Society,1995,78(08):2101-2112. |
| [32] | Viehland D;Forst D;Li J F .Compositional Heterogeneity and the Origins of the Multicell Cubic State in Sn-doped Lead Zirconate Titanate Ceramics[J].Journal of Applied Physics,1994,75(08):4137-4143. |
| [33] | Chang Y J .TEM study of Crystal and Domain Structures of Nb-doped 95/5 PZT Ceramics[J].Applied Physics A:Materials Science and Processing,1982,29:237-244. |
| [34] | Yang P.;Payne DA. .THE EFFECT OF EXTERNAL FIELD SYMMETRY ON THE ANTIFERROELECTRIC-FERROELECTRIC PHASE TRANSFORMATION[J].Journal of Applied Physics,1996(7):4001-4005. |
| [35] | Yang P;David A Payne .Thermal Stability of Field-forced and Field-assisted Antiferroelectric-Ferroelectric Phase Transformations in Pb(Zr,Sn,Ti)O3[J].Journal of Applied Physics,1992,71(03):1361-1367. |
| [36] | Pan W Y;Zhang Q M;Bhalla A et al.Field-forced Antiferroelectric-to-ferroelectric Switching in Modified Lead Zirconate Titanate Stannate Ceramics[J].Journal of the American Ceramic Society,1989,72:571-578. |
| [37] | Berlincourt D;Jaffe H;Krueger H H A et al.Release of Electric Energy in PbNb(ZrTiSn)O3 by Temperature and by Pressure-enforced Phase Transitions[J].Applied Physics Letters,1963,3(05):90-92. |
| [38] | 杨同青 .Pb(Zr,Sn,Ti)O<,3>反铁电陶瓷的场诱相变性能研究[D].西安交通大学,1999. |
| [39] | Brooks K G;Chen J;Udayakumar K R et al.Electric and Field Forced Phase Switch in La-modified Lead Zirconate Titanate Stannate Thin Films[J].Journal of Applied Physics,1994,75(03):1699-1704. |
| [40] | Jae Hyuk Jang;Ki Hyun Yoon .Effect of antiferroelectric buffer on electric fatigue and leakage in ferroelectric Pb(Zr, Sn, ti)NbO_3 thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2001(1/2):67-72. |
| [41] | Li X;Zhai JW;Chen HD .(Pb,La)(Zr,Sn,Ti)O-3 antiferroelectric thin films grown on LaNiO3-buffered and Pt-buffered silicon substrates by sol-gel processing[J].Journal of Applied Physics,2005(2):4102-1-4102-7-0. |
| [42] | Service R E .Shape-changing Crystals Get Shiftier[J].Science,1997,275:1878. |
| [43] | Shebanov L;Kusnetsov M .Electric Field-induced Antiferroelectric-to-ferroelectric Phase Transition in Lead Zirconate Titanate Stannate Ceramic Modified With Lanthanum[J].Journal of Applied Physics,1994,76:4301-4304. |
| [44] | Lee J H;Chiang Y M .Pyrochlore-perovskite Phase Transformation in Highly Homogeneous (Pb,La)(Zr,Sn,Ti)O3 Powders[J].Journal of Materials Chemistry,1999,9:3107-3111. |
| [45] | 薛丽红,张一玲,李强,郭泉泳,刘锐.共沉淀法制备复合钙钛矿结构PLZST的研究[J].无机材料学报,2004(03):566-570. |
| [46] | L. XUE;Q. LI;Y. ZHANG .Synthesis, sintering and characterization of PLZST perovskite prepared by a lactate precursor route[J].Journal of the European Ceramic Society,2006(3):323-329. |
| [47] | Xue L H;Li Q;Zhang Y L et al.Synthesis and Characterization of PLZST Prepared by Coprecipitation[J].Journal of Materials Science,2005,40:2697-2699. |
| [48] | Xue LH;Li Q;Zhang YL;Zhen XH;Liu R;Wang L .Flux growth of (Pb,La)(Zr, Sn,Ti)O-3 single crystals and their characterization[J].Journal of Crystal Growth,2005(3/4):378-383. |
| [49] | 薛丽红 .复合钙钛矿相PLZST弛豫反铁电材料合成与晶体生长[D].清华大学,2005. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%