对自由能取极小可得到一系列方程,原则上可以确定任意系统相变时的行为.在105K SrTiO3发生立方一四方的反铁畸变,考虑量子效应,从吉布斯自由能形式出发,计算了介电常数,并讨论低温时的居里一外斯行为.
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