用动电位连续扫描法制备了聚(2,2'-二氨基苯氧基二硫化物)(PDAPO),通过FT-IR, FT-Raman,XPS等测试技术确证其结构. 聚合物产物与其单体的循环伏安实验结果表明,由于PDAPO结构中支链聚苯胺的电催化作用和强供电子键-O-S-S-O-的作用,其氧化还原反应的可逆性优于其它同类的聚有机二硫化物. 研究了聚合物的导电性能、热稳定性及表面状态. 结果表明,PDAPO是一种新型高电活性的导电聚合物,可用作锂或锂二次电池的正极材料.
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