对Zn-PTFE(聚四氟乙烯)复合电极的复合电沉积过程进行研究,并考察了它在电合成频那醇上的应用.实验结果表明:控制镀液中PTFE悬浮量为30mL/L,镀液温度25℃,以5.0A/dm2电流密度电沉积22.5C,可制备出PTFE微粒分散均匀的复合电极;以此复合电极为阴极电合成频那醇,产率可达53.6%,明显高于Zn电极的25.1%.
A Zn-PTFE(Zinc-polytetrafluoroethylene) composite electrode withwell-dispersed PTFE fine particle has been prepared in conditions of 5.0 A/dm2, 22.5C, and PTFE 30 mL/L at 25 ℃. The composite electrode was used as cathode in electrosynthesis of pinacol from acetone in yield of 53.6%, much higher than that by using Zn electrode as cathode(25.1%).
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