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采用低压化学气相沉积法(LPCVD)以铜箔为生长衬底来制备石墨烯.XRD表征得石墨烯生长前后铜箔衬底主要为(100)晶面,而且铜箔在高温下退火晶粒明显长大有利于高质量石墨烯的生长.拉曼光谱表明所制备的石墨烯为双层结构.通过转移、刻蚀等工艺制备了石墨烯场效应晶体管(G-FET)原型器件,其转移特性曲线(IDS-VGS)表明所制备的石墨烯表现为p型输运特性.在器件中石墨烯的XPS图谱说明了石墨烯吸附有有机物基团,导致p型特性的部分原因.同时本文研究了真空退火对G-FET器件性能的影响,结果表明:退火温度为200℃时,G-FET的空穴载流子迁移率最佳;而随着温度增加,开关比(ON-OFF ratio)在不断减小,载流子迁移率迅速在降低.

参考文献

[1] Chen JH;Jang C;Xiao SD;Ishigami M;Fuhrer MS .Intrinsic and extrinsic performance limits of graphene devices on SiO2[J].Nature nanotechnology,2008(4):206-209.
[2] Maeng, I.;Lim, S.;Chae, S.J.;Lee, Y.H.;Choi, H.;Son, J.-H. .Gate-controlled nonlinear conductivity of Dirac fermion in graphene field-effect transistors measured by terahertz time-domain spectroscopy[J].Nano letters,2012(2):551-555.
[3] Damon B. Farmer;Yu-Ming Lin;Phaedon Avouris .Graphene field-effect transistors with self-aligned gates[J].Applied physics letters,2010(1):013103-1-013103-3.
[4] Li X;Wang X;Zhang L;Lee S;Dai H .Chemically derived, ultrasmooth graphene nanoribbon semiconductors.[J].Science,2008(5867):1229-1232.
[5] Cohen-Karni, T;Qing, Q;Li, Q;Fang, Y;Lieber, CM .Graphene and Nanowire Transistors for Cellular Interfaces and Electrical Recording[J].Nano letters,2010(3):1098-1102.
[6] Liao, L.;Bai, J.;Cheng, R.;Lin, Y.-C.;Jiang, S.;Qu, Y.;Huang, Y.;Duan, X. .Sub-100 nm channel length graphene transistors[J].Nano letters,2010(10):3952-3956.
[7] Bonaccorso, F.;Sun, Z.;Hasan, T.;Ferrari, A.C. .Graphene photonics and optoelectronics[J].Nature photonics,2010(9):611-622.
[8] Liu, M.;Yin, X.;Zhang, X. .Double-layer graphene optical modulator[J].Nano letters,2012(3):1482-1485.
[9] 100-GHz Transistors from Wafer-Scale Epitaxial Graphene[J].Science,2010(Feb.5 TN.5966):662.
[10] A Micromachined Nanopositioner With On-Chip Electrothermal Actuation and Sensing[J].IEEE Electron Device Letters,2010(10):1161.
[11] Hernandez Y;Nicolosi V;Lotya M;Blighe FM;Sun ZY;De S;McGovern IT;Holland B;Byrne M;Gun'ko YK .High-yield production of graphene by liquid-phase exfoliation of graphite[J].Nature nanotechnology,2008(9):563-568.
[12] Kwon, SY;Ciobanu, CV;Petrova, V;Shenoy, VB;Bareno, J;Gambin, V;Petrov, I;Kodambaka, S .Growth of Semiconducting Graphene on Palladium[J].Nano letters,2009(12):3985-3990.
[13] Sutter PW;Flege JI;Sutter EA .Epitaxial graphene on ruthenium[J].Nature materials,2008(5):406-411.
[14] Coraux J;N'Diaye AT;Busse C;Michely T .Structural coherency of graphene on Ir(111)[J].Nano letters,2008(2):565-570.
[15] Eom, D;Prezzi, D;Rim, KT;Zhou, H;Lefenfeld, M;Xiao, S;Nuckolls, C;Hybertsen, MS;Heinz, TF;Flynn, GW .Structure and Electronic Properties of Graphene Nanoislands on Co(0001)[J].Nano letters,2009(8):2844-2848.
[16] Ishigami M;Chen JH;Cullen WG;Fuhrer MS;Williams ED .Atomic structure of graphene on SiO2[J].Nano letters,2007(6):1643-1648.
[17] Wang, HL;Robinson, JT;Li, XL;Dai, HJ .Solvothermal Reduction of Chemically Exfoliated Graphene Sheets[J].Journal of the American Chemical Society,2009(29):9910-9911.
[18] Graphene-On-Silicon Schottky Junction Solar Cells[J].Advanced Materials,2010(25):2743-748,2724.
[19] Ferrari AC;Meyer JC;Scardaci V;Casiraghi C;Lazzeri M;Mauri F;Piscanec S;Jiang D;Novoselov KS;Roth S .Raman spectrum of graphene and graphene layers[J].Physical review letters,2006(18):7401-1-7401-4-0.
[20] Gao, L.;Ren, W.;Liu, B.;Saito, R.;Wu, Z.-S.;Li, S.;Jiang, C.;Li, F.;Cheng, H.-M. .Surface and interference coenhanced Raman scattering of graphene[J].ACS nano,2009(4):933-939.
[21] Zhao, L.;Rim, K.T.;Zhou, H.;He, R.;Heinz, T.F.;Pinczuk, A.;Flynn, G.W.;Pasupathy, A.N. .Influence of copper crystal surface on the CVD growth of large area monolayer graphene[J].Solid State Communications,2011(7):509-513.
[22] Wofford, J.M.;Nie, S.;McCarty, K.F.;Bartelt, N.C.;Dubon, O.D. .Graphene islands on Cu foils: The interplay between shape, orientation, and defects[J].Nano letters,2010(12):4890-4896.
[23] Romero, H.E.;Shen, N.;Joshi, P.;Gutierrez, H.R.;Tadigadapa, S.A.;Sofo, J.O.;Eklund, P.C. .n-type behavior of graphene supported on Si/SiO_2 substrates[J].ACS nano,2008(10):2037-2044.
[24] Cheng, Z.;Zhou, Q.;Li, Q.;Wang, C.;Fang, Y. .Toward intrinsic graphene surfaces: A systematic study on thermal annealing and wet-chemical treatment of SiO2-supported graphene devices[J].Nano letters,2011(2):767-771.
[25] 蔡宏中,魏巧灵,陈力,王云,胡昌义.CVD温度对钽涂层组成、显微组织及形貌的影响[J].稀有金属,2012(04):563-567.
[26] 张心强,屠海令,杜军,杨萌萌,赵鸿滨,杨志民.Gd2O3-HfO2栅介质薄膜的外延制备及Ge-MOS电学特性分析[J].稀有金属,2012(03):405-409.
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