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对碳电热还原法生产的共晶铝硅合金加锰自然沉降法除铁进行了研究.通过差热热重及对自然沉降后获得的合金富铁相成分进行分析,结果表明:共晶铝硅合金加锰后,锰会与合金中的富铁相结合,增大富铁相的密度,提高富铁相的初晶温度;当合金中Mn/Fe达到1以上时,富铁相的初晶温度提高100℃以上;当富铁相中锰含量大于10%时,多呈块状,利于沉降到合金熔体底部,当锰含量低于6%时,富铁相多为针状留在合金中.通过加锰自然沉降可将合金中60%以上的富铁相去除.

The removing iron process by natural deposition of cuteetic Al-Si alloys produced by carbothermal reduction was studied.The TG-DAT curve and scanning electronic microscopy of iron-rich phases in Al-Si alloy Was analyzed.The results showed that after adding manganese in Al-si alloy,the manganese could form intermetallic phases with iron-rich phases.and increased the density of iron-rich phases,and increased the primary crystallization temperature of iron-rich phases.When the ratio of Mn/Fe Was higher than one,the primary crystallization temperature increased more than 100℃.When the content of manganese was more than 10%,the iron-rich phases were mostly massive and could deposit easily to the bottom.When the content of manganese was lower than 6%,the iron-rich phases were mostly bulky spicula and remained inthe alloy.More than 60% of iron-rich phases was removed by natural deposition.

参考文献

[1] YOU Jing,WANG Yao-wu,FENG Nai-xiang,YANG Ming-sheng.Preparation of casting alloy ZL101 with coarse aluminum-silicon alloy[J].中国有色金属学会会刊(英文版),2008(01):116-120.
[2] 周晓霞,张仁元,刘银峁.铝硅合金中铁相存在的形态及影响其形成的因素[J].广东有色金属学报,2003(01):51-54.
[3] Yi J Z;Gao Y X;Lee P D .Effect of Fe-content on fatigue crack initiation and propagation in a cast aluminum-silicon alloy (A356-T6)[J].Materials Science and Engineering A,2004,386:396.
[4] 王铁宝,齐向前,王晓东,刘春阳.稀土对3X04铝合金铸态组织及性能的影响[J].稀有金属,2008(04):425-428.
[5] Dinnis Cameron M;Taylor John A;DaMe Arne K.Iron-related porosity in Al-Si-(Cu) foundry alloys[J].Materials Science and Engineering,2006(03):11.
[6] Narayanan L A;Samuel F H;Gruzleski J E.Crystallization behavior of Iron-containing intermetallic compouds in 319 aluminium alloys[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1992(25A):1761.
[7] Stoichev N.;Kovachev P.;Momchilova E.;Yaneva S. .Kinetics of structural coarsening of microcrystalline Al-Si-Mg alloys during thermal treatment and compacting[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,1998(3):483-487.
[8] 印飞,杨江波,孙宝德.高含铁量铝硅合金中铁相的凝固行为与形貌控制[J].上海交通大学学报,2002(01):43-46,50.
[9] Gravitional Gobrecht J .Separation of Fe and Mn in Al-Si alloys[J].Giesserei,1975,62(10):263.
[10] 张磊,焦万丽,尉海军,姚广春.锰结合预先热处理对铝硅合金中富铁相组织和力学性能的影响[J].中国有色金属学报,2005(03):368-373.
[11] Yao Guangchun.Producing Al-Si Alloy by Carbothermal Reduetion[M].沈阳:东北大学出版社,1998:206.
[12] Colwell D L;Kissing R J.Die and perment mold casting aluminium alloy minor elements[J].AFS Transactions,1961(69):610.
[13] Dinnis Cameron M;Taylor John A;Dahle Arne K.Iron-related porosity in Al-Si-(Cu) foundry alloys[J].Materials Science and Engineering,2006(03):11.
[14] 日本长崎诚三;平林真;刘安生.二元合金状态图集[M].北京:冶金工业出版社,2004:36.
[15] Xu Zhenming;Li Tianxiao;Zhou Yaohe .Elimination of Fe in Al-Si cast alloy scrap by electromagnetic filtration[J].Journal of Materials Science,2003,38:4557.
[16] 谭天恩;麦本熙;丁惠华.化工原理[M].北京:化学工业出版社,2004:128.
[17] 郭景杰.合金熔体及其处理[M].北京:机械工业出版社,2005:18.
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