Cu-In体系的热力学优化

稀有金属, 2007, 31(6): 807-812. doi: 10.3969/j.issn.0258-7076.2007.06.018

Cu-In体系的热力学优化

曹松 ^1, , 黄松涛 ^2, , 储茂友 ^3, , 岳强 ^4, , 沈剑韵 ^5,

1.北京有色金属研究总院矿物资源与冶金材料研究所,北京,100088

2.北京有色金属研究总院矿物资源与冶金材料研究所,北京,100088

3.北京有色金属研究总院矿物资源与冶金材料研究所,北京,100088

4.北京有色金属研究总院矿物资源与冶金材料研究所,北京,100088

5.北京有色金属研究总院矿物资源与冶金材料研究所,北京,100088

基金项目: 国家自然科学基金(50672012)

关键词： Cu-In , 相图计算 , 热力学优化

Thermodynamic Optimization of Cu-In System

评估了Cu-In体系的相平衡和热力学实验结果, 并对体系进行了热力学优化. 采用替代模型描述体系的液相和富铜固溶体相, 双亚晶格模型描述线性化合物相, 三亚晶格模型描述非线性化合物相, 结合选取合理的实验数据, 优化得到Cu-In体系各相的热力学参数, 用优化结果计算的相图以及热力学性质与实验结果吻合.

参考文献

[1]	Subramanian P R;Laughlin D E .The Cu-In (copper-indium) system[J].Bulletin of Alloy Phase Diagrams,1989,10:554.
[2]	Weibke F;Eggers H .The phase diagram of the system copper-indium[J].Zeitschrift Fur Anorganische Und Allgemeine Chemie,1934,220:273.
[3]	Hume-Rothery W;Raynor G V;Packer K K .The constitution and structure of alloys of intermediate composition in the systems copper-indium,copper-aluminum,copper-germanium[J].Journal of the Institute of Metals,1940,66:209.
[4]	Owen E A;Morris D P .The application of X-ray methods to the determination of phase boundaries in metallurgical equilibrium diagrams[J].Journal of the Institute of Metals,1950,76:145.
[5]	Reynolds J;Wiseman W A;Hume-Rothery W .The equilibrium diagram of the system copper-indium in the region 25%～35% indium[J].Journal of the Institute of Metals,1952,80:637.
[6]	Jones R O;Owen E A .X-ray determination of the alpha-phase boundary of the copper-indium alloy system[J].Journal of the Institute of Metals,1954,82:445.
[7]	Straumanis M E;Yu L S .Lattice parameters,densities,expansion coefficients and perfection of structure of Cu2In α phase[J].Acta Crystallographica Section A:Foundations of Crystallography,1969,25:676.
[8]	Jain K C;Ellner M;Schubert K .On the phases occurring near the composition Cu64In36[J].Zeitschrift fur Metallkunde,1972,63(08):456.
[9]	Kim H S .Crystal structure studies of alloys InMn3,γCu-In,δCu-In and γ3 Au-Zn[D].Physics,University of Waterloo,Waterloo,Ontario,Canada,1980.
[10]	Rajasekharan T P;Schubert K .Crystal structure of Cu11In9[J].Zeitschrift Fur Metallkunde,1981,72:275.
[11]	Bolcavage A;Chen S W;Kao C R;Chang Y A,Romig Jr A D .Phase equilibria of the Cu-In system.I.experimental inverstigation[J].Journal of PHASE EQUILIBRIA,1993,14:14.
[12]	Kang T;Kehaiain H V;Castanet R .Thermodynamic study of the copper-indium binary system.2.potentiometric study[J].Journal of the Less-Common Metals,1977,53:153.
[13]	Bahari Z;Dichi E;Legendre B .Heat content and heat capacity of Cu0.7In0.3 from 298 K to 1273 K[J].Zeitschrift fur Metallkunde,1999,90:55.
[14]	Kameda K .Activity measurements of liquid Cu-In alloys by EMF using zirconia electrolyte[J].Journal of the Japan Institute of Metals,1990,54:54.
[15]	Kao C R;Bolcavage A;Chen S L;Chen S W,Chang Y A,Romig Jr A D .Phase equilibria of the Cu-In system.I.experimental investigation[J].Journal of PHASE EQUILIBRIA,1993,14:22.
[16]	Jean Hertz;Khadija El Aissaoui;Lahcen Bouirden .A Thermodynamic Optimization of the Cu-In System[J].Journal of Phase Equilibria,2002(6):473-479.
[17]	H.S. Liu;X.J. Liu;Y. Cui .Thermodynamic Assessment of the Cu-In Binary System[J].Journal of Phase Equilibria,2002(5):409-415.
[18]	Zahra Bahari;Emma Dichi;Bernard Legendre .The equilibrium phase diagram of the copper-indium system:a new investigation[J].Thermochimica Acta,2003,401:131.
[19]	Dinsdale A T .SGTE data for pure elements[J].CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,1991,15:317.
[20]	Sundman B;Jansson B;Anderson J O .Thermocalc databank system[J].CALPHAD-Computer Coupling of Phase Diagrams and Thermochemistry,1985,9:153.
[21]	储茂友,郭江贵,商顺利,孙军,沈剑韵.W-Zr体系的热力学优化[J].稀有金属,2003(06):701-705.
[22]	Muschik T;Hehenkamp T .Solid-liquid-equilibria on the Cu-side of the Cu-In system[J].Zeitschrift fur Metallkunde,1987,78(05):358.
[23]	Kang T;Kehaiain H V;Castanet R .Thermodynamic study of the copper-indium binary system.I.calorimetric study[J].J Calorim Anal Therm,1976,7(3-7):1.
[24]	Vinokurova G A;Geiderikh V A .Thermodynamic properties of indium-copper alloys[J].Zhurnal Fizicheskoi Khimii,1976,50:1661.
[25]	Bolcavage A;Chen S W;Kao C R;Chang Y A,Romig Jr A D .Phase equilibria of the Cu-In system.I.experimental investigation[J].Journal of PHASE EQUILIBRIA,1993,14(01):14.
[26]	Okamoto H .Cu-In (copper-indium)[J].Journal of Phase Equilibria,1991,12(06):702.
[27]	Wallbrecht P C;Blachnik R;Mills K C .The heat capacity and enthalpy of some hume-rothery phases formed by copper,silver and gold.Part Ⅲ.Cu+Ga,Ag+Ga,Au+Ga,Cu+In,Ag+In and Au+In systems[J].Thermochimica Acta,1981,48:69.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Cu-In体系的热力学优化

Thermodynamic Optimization of Cu-In System

参考文献