在分析现有氯化浸金体系的基础上, 对氯化浸金过程进行热力学分析, 得出了体系的共性规律. 金的氯化浸出是一个氧化络合过程, 其氧化电位取决于生成的金氯络合物的稳定常数和特定的浸出条件. 在标准条件下, 只要氧化剂的标准电极电位高于0.99 V, 金将以三价金氯络合物的形态浸出;当氧化剂的标准电极电位高于1.12 V, 金将以一价金氯络合物的形态浸出. 热力学上更有利于金以三价金氯络合物的形态浸出. 加大络合剂、氧化剂的浓度和/或不断降低浸出液中金氯络合物的浓度, 热力学上有利于金的浸出.
参考文献
[1] | Habashi F.Principles of Extractive Metallurgy[M].New York:Gordon and Breach,1980:39. |
[2] | 李俊萌.难处理金矿石预处理方法研究现状及其发展趋势[J].稀有金属,2003(04):478-481,490. |
[3] | 黄怀国,江城,孙鹏,陈景河,邹来昌.碱性(石灰)热压氧化预处理难浸金矿工艺的机理研究[J].稀有金属,2003(02):249-253. |
[4] | 李德良,黄念东,许中坚,毛谙章.Grain Size and Wettability of TiO2/SiO2 Photocatalytic Composite Thin Films[J].稀有金属,2001(02):81-86. |
[5] | 杨华明,邱冠周.细磨氰化浸金新工艺的研究[J].稀有金属,1999(01):13-15. |
[6] | 李桂春,卢寿慈.非氰化提金技术的发展[J].中国矿业,2003(03):1-5. |
[7] | 李德良,唐鹤,黄念东.论氰化物替代物研究的发展前景[J].湘潭矿业学院学报,1998(03):30-35,94. |
[8] | L.F.Kozin;V.T.Melekhin .Extraction of Gold From Ores and Concentrates by Leaching with the Use of Cyanides and Alternative Reagents[J].Russian journal of applied chemistry,2004(10):1573-1592. |
[9] | Vinals J;Núnez C;Herreros O .Kinetics of the aqueous chlorination of gold in suspended qarticles[J].HYDROMETALLURGY,1995,38(02):125. |
[10] | 李希明;柯家骏.一氯化法提金的热力学分析[J].金银专刊,1991(01):40. |
[11] | 彭铁辉 .氯化铁溶液浸出金的热力学分析[J].黄金,1990,11(08):30. |
[12] | 李民权,关玉蓉.氯化浸金机理研讨[J].黄金,2003(02):35-38. |
[13] | Nesbitt C C;Milosavljevic E B;Hendrix J L .Determination of the mechanism of the chlorination of gold in aqueous solutions[J].Industrial and Engineering Chemistry Research,1990,29(08):1696. |
[14] | Bünyamin Donmez;Zafer Ekinci;Cafer Celik et al.Optimization of the chlorination of gold in decopperized anode slime in aqueous medium[J].Hydrometallurgy,1999,52(01):81. |
[15] | Puvvada G.V.K.;Murthy D.S.R. .Selective precious metals leaching from a chalcopyrite concentrate using chloride/hypochlorite media[J].Hydrometallurgy,2000(3):185-191. |
[16] | Li Ximing;Ke Jiajun;Meng Xinhui et al.Chlorine leaching of gold-bearing sulphide concentrate and its calcine[J].HYDROMETALLURGY,1992,29(1-3):205. |
[17] | Greaves J N;Palmer G R;White III W W .The recovery of gold from refractory ores by the use of carbon-in-chlorine leaching[J].Journal of The Minerals,Metals & Materials Society,1990,42(09):12. |
[18] | Mcdonald G W;Saud A;Barger M S et al.The fate of gold in cupric chloride hydrometallurgy[J].HYDROMETALLURGY,1987,18(03):321. |
[19] | 李东亮,张良,韩选利,张银菊.二氧化氯浸金实验研究[J].西安建筑科技大学学报(自然科学版),2002(02):187-190,200. |
[20] | 徐家振,符岩,金哲男,裘治华,赵永,奚英洲.氯酸钠氯化提金的研究[J].材料与冶金学报,2002(01):77-80. |
[21] | 方兆珩.碳质微细粒浸染型金矿的直接氯化浸出工艺[J].黄金科学技术,2002(02):29-34. |
[22] | 张文明.常温氯化法从拜尔废催化剂中回收金钯[J].贵金属,2001(03):26-29. |
[23] | 夏木西卡玛尔;阿不里米提;王菊芳 等.催化氯化法浸金研究[J].黄金,1997,18(09):37. |
[24] | 中南矿冶学院分析教研室.化学分析手册[M].北京:科学出版社,1982:590. |
[25] | Kelsall G H;Welham N J;Diaz M A .Thermodynamics of Cl-H2O,Br-H2O,I-H2O,Au-Cl-H2O,Au-Br-H2O and Au-I-H2O systems at 298 K[J].Journal of Electroanalytical Chemistry,1993,361:13. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%