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用均匀设计试验方法设计系列含Fe低Co AB5型贮氢合金B侧配比, 以放电容量、活化次数、容量保持率及放电平台中值电位为多目标函数, 采用逐步回归分析方法和最小二乘法及黄金分割一维寻优手段进行最优化处理, 确定了最优化的B侧合金元素的摩尔比: Mm0.8La0.2Ni4.0Mn0.5Al0.3Co0.37Fe0.13(AB5.3).新型含Fe低Co MmB5型贮氢合金是单相CaCu5型结构, Co含量为4.97%, 放电容量达307.3 mAh·g-1(极片), 活化次数为两次, 500次循环后容量保持率为78.9%, 高温容量为277.2 mAh·g-1(55 ℃), 低温容量为197.3 mAh·g-1(-30 ℃), 3C放电容量为275.4 mAh·g-1.

参考文献

[1] Willems J J G;Buschow K H J .From permanent magnets to rechargeable hydride electrodes[J].Journal of the Less-Common Metals,1987,129:13.
[2] Co对MlNi4.3-xCoxAl0.7贮氢电极动力学性能的影响[J].中国有色金属学报,1999(03):453.
[3] Lichtenberg F;Koheler U;Folaer A et al.Development of AB5 hydrogen storage alloys with low-Co content for rechargeable Ni-MH batteries with respect to electric vehicle applications[J].Journal of Alloys and Compounds,1997,253:570.
[4] Osumi Y;Suzuki H;Kato A et al.Hydrogen absorption-desorption characteristics of misch metal-nickel-silicon alloys[J].Journal of the Less-Common Metals,1982,84:99.
[5] Cocciantelli J M;Bernard P;Fernandez S et al.The influence of Co and various additives on the perform ance of Mm4.3-xMn0.33Al0.4Cox hydrogen storage alloys and Ni/MH prismatic sealed cells[J].Journal of Alloys and Compounds,1997,253-254:642.
[6] Hu WK.;Jang KJ.;Lee JY.;Kim DM. .Studies on Co-free rare-earth-based hydrogen storage alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):254-258.
[7] Fukumoto Y;Miyamoto A;Matsuoka M et al.Effect of the stoichiometric ratio on electrochemical properties of hydrogen storage alloys for nickel-metal hydride batteries[J].Electrochimica Acta,1995,40(07):845.
[8] Cocciantelli J M;Bernard P;Fernandez S et al.The influence of Co and various additives on the performance of MmNi4.3-xMn0.33Al0.4Cox hydrogen storage alloys and Ni/MH prismatic sealed cells[J].Journal of Alloys and Compounds,1997,253-254:642.
[9] Maeda T;Shinya N;Shima S .Symposium on Rare Earths[J].The Rare Earth Society of Japan,2000,36:220.
[10] 吕建国,黄靖云,叶志镇.AB5型贮氢合金及其优化设计[J].金属功能材料,2001(04):5-12.
[11] 张羊换,王新林,陈梅艳,李平,林玉芳,李蓉.高性能AB5型贮氢合金的成分设计[J].金属功能材料,2002(05):1-6.
[12] Khaldi C;Mathlouthi H;Lamloumi et al.Effect of partial substitution of Co with Ee on the properties of LaNi3.55Mn0.4Al0.3Co0.75-xFex(x=0, 0.15, 0.55) alloys electrodes[J].Journal of Alloys and Compounds,2003,360:266.
[13] 于丽敏,蒋文全,傅钟臻,蒋利军.AB5型贮氢合金结构分析[J].稀有金属,2004(06):1060-1064.
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