层状Ni-Mn基锂离子电池正极材料具有层状结构镍酸锂(LiNiO2)的高比容量以及尖晶石型结构锰酸锂(LiMn2O4)的高安全性、低价格等特点, 是最有可能代替或部分代替LiCoO2的新型正极材料用于小型锂离子电池, 同时也可望用作低成本、高安全性和大容量动力型锂离子电池的正极材料. 本文综述了层状Li-Ni-Mn-O系化合物和LiNi1/3Mn1/3Co1/3O2的合成工艺、结构特点和电化学性能, 阐述了层状Ni-Mn基锂离子电池正极材料的发展、研究开发现状和应用前景.
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