欢迎登录材料期刊网

材料期刊网

高级检索

对铸态和快淬态贮氢合金Mm(NiCoMnAl)5.1B0.1的微观组织和电化学性能进行了研究. 发现快淬态合金基本上消除了第二相, 快淬合金组织中存在一定比例的非晶相, 并且随着淬速增加非晶相的量增多; 与铸态合金相比, 快淬态合金的放电容量有所降低, 但循环寿命显著提高, 这主要是由于快淬导致晶粒细化和形成一定数量的非晶态组织.

参考文献

[1] 王志兴,李新海,陈启元,郭炳昆,彭文杰,郭华军.含锡AB5型非化学计量贮氢合金Ⅰ.合金的结构[J].中国稀土学报,2000(02):128-130.
[2] 文明芬,翟玉春,陈廉,佟敏,陈德敏,郑华,马荣俊.快淬Zr0.9T i0.1(N i,Co,Mn,V)2.1贮氢合金的结构与性能[J].过程工程学报,2001(04):408-411.
[3] Mishima R;Miyamura H;Sakai T et al.Hydrogen storage alloys rapidly solidified by the melt-spinning and their characteristics as metal hydride electrodes[J].Journal of Alloys and Compounds,1993,192:176.
[4] Nakamura Y;Nakamura H;Fujitani S et al.Homogenizing behaviour in a hydrogen absorbing LaNi4 55Al0 45 alloy through annealing and rapid quenching[J].Journal of Alloys and Compounds,1994,210:299.
[5] LI C J;Wang X L .The temperature features of the rapidly quenched Mm(NiCoMnTi)5 alloy as a negative electrode[J].Journal of Alloys and Compounds,1999,282:225.
[6] 郑群,陈云贵,王金国,陶明大,唐定骧,涂铭旌.退火处理对快淬贮氢合金显微组织及电化学性能的影响[J].中国稀土学报,2003(04):417-420.
[7] 李丽,吴锋,杨凯.Degradation Behavior of Electrochemical Performance of Sealed-Type Nickel/Metal Hydride Batteries[J].稀土学报(英文版),2003(03):341-346.
[8] Wu Chaoling;Chen Yungai et al.Electrochemical properties of strip coating LPCNi3 55Mn0 4Al0 3 hydrogen storage alloys[J].稀土学报(英文版),2002,20(05):517.
[9] 王秋娟,李全安,陈云贵,涂铭旌.快淬对贮氢合金组织和电化学性能的影响[J].洛阳工学院学报(自然科学版),2001(02):8-11.
[10] Ye H;Zhang H;Wu W Q et al.Influence of the boron additive on the structure thermodynamics and electrochemical properties of the MmNi3 55Co0 75Mn0 4Al0 3 hydrogen storage alloy[J].Journal of Alloys and Compounds,2000,312:68.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%