选用磷酸锌为主要防锈颜料,协同云母氧化铁灰,制备无溶剂型环氧防腐涂料.考察涂层的基本性能,并采用交流阻抗(EIS)测试技术,分析了颜料体积浓度(PVC)、活性稀释剂和防锈颜料质量比对涂层防腐性能的影响.实验结果表明:该涂料固含量高达98%以上,是环境友好型涂料;PVC小于12%时,涂层具有较好的防腐性能;PVC为8%,活性稀释剂添加量为2%,云铁灰与磷酸锌质量比为1:4时涂层的防腐性能最佳.在涂层浸泡一定时间后,磷酸锌能防止腐蚀的进一步发生,起到有效抑制腐蚀的作用.
参考文献
| [1] | 秦国治,田志斌.无溶剂环氧及其改性防腐蚀涂料综述[J].现代涂料与涂装,2002(02):31-33. |
| [2] | Blustein G;Deya MC;Romagnoli R;del Amo B .Three generations of inorganic phosphates in solvent and water-borne paints: A synergism case[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2005(5):1386-1397. |
| [3] | BETHENCOURT M;BOTANA F J;MARCOS M et al.Inhibitor properties of"green"pigments for paills[J].Progress in Organic Coatings,2003,46:280-282. |
| [4] | de Lima-Neto P;de Araduo AP;Araujo WS;Correia AN .Study of the anticorrosive behaviour of epoxy binders containing non-toxic inorganic corrosion inhibitor pigments[J].Progress in Organic Coatings: An International Review Journal,2008(3):344-350. |
| [5] | DEYA M;DI SARLI A R;DEL AMO B et al.Performance of antioarresive coatings containing tripolyphosphates in aggressive environrnents[J].Industrial and Engineering Chemistry Research,2008,47:7038-7047. |
| [6] | GONZ(A)LEZ S;GIL M A;HDRN(A)NDEZ J O et al.Resistance to cerrosion of galvanized steel covered with all epoxy-polyamide primer coating[J].Progress in Organic Coatings,2001,41(1-3):167-170. |
| [7] | MANSFELD F .Models for the impedance behavior of protective coatings and cases of localized corrosion[J].Electrochimica Acta,1993,38(14):1891-1897. |
| [8] | 张树永,罗小雯,李善君,周伟舫.电化学阻抗法研究降低环氧涂层的吸水性能[J].化学学报,1999(03):329-332. |
| [9] | WANG T;TAN Y J .Understanding electredeposition of polyaniline coatings for corrosion prevention applications using the wire beam electrode method[J].Corrosion Science,2006,48:2274-2290. |
| [10] | 曹楚南.腐蚀电化学原理[M].北京:化学工业出版社,2004:218-221. |
| [11] | 刘安华.涂料技术导论[M].北京:化学工业出版社,2005:87. |
| [12] | 何金花,张鑫,高延敏.磷酸锌对涂层耐腐蚀性能的影响[J].全面腐蚀控制,2008(01):42-43,41. |
| [13] | 张微,龙军峰,苏志坚.环氧云铁防腐涂层的研制[J].上海涂料,2007(05):14-15. |
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