水分散体系中原子转移自由基聚合(ATRP)具有自由基聚合、乳液聚合和活性/可控聚合的优点,因此近年来关于水分散体系中ATRP的研究日益增多.本文综述了近年来水分散体系(包括乳液体系、细乳液体系、微乳液体系)中原子转移自由基聚合的研究进展,对应用在水分散体系中的几种ATRP反应机理做了简要介绍,包括正向AT-RP、反向ATRP(RATRP)、正向/反向同时进行的(SR&NI)ATRP、电子转移活化剂(AGET)ATRP,并对RATRP、SR&NI、ATRPAGET ATRP的优缺点进行了总结.
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