多异氰酸酯不仅具有交联聚合物的作用,还能保持聚合物的完整形态.本文对被刮擦过的脂肪族聚氨酯体系的自我修复行为的研究为能量具体修复指数提供了起点,描述了聚氨酯体系的自我修复功能,而使聚合物体系具有形态记忆效应.
Polyisocyanates can not only crosslink polymers,but also help to keep them intact.Studies of the self-recovery behavior of aliphatic polyurethane systems after scratching provided the starting point for analysis of energy-specific recovery index.This article described the self-healing capability of polyurethane systems,which consequently provides the polymer shape-memory effect.
参考文献
[1] | GUENTER OERTEIL.Polyurethane plastic handbook (7)[M].Munich:Carl Hanser Publishing House,1993 |
[2] | ULRICH MEIER-WESTHUES.Polyurethanes coatings,adhesives and sealants[M].Hannover:Vincentz Network,2007 |
[3] | MARKUS MECHTEL.Possibilities with high functional aliphatic polyisocyanates[A].Berlin,Germany,2008 |
[4] | U.Meier-Westhues .On the road to improved scratch resistance[J].European Coatings Journal,2002(9):28-29,32-34-0. |
[5] | HANS-JOACHIM STREITBERGER;KARL-FRIEDRICH DOSSEL.Automotive paints and coatings[M].Weinheim,Wiley-VCH Publishing House,2008 |
[6] | THOMAS B(A)KER.Polyaspartic-innovative binders for cost effective coating concepts[A].,2008 |
[7] | WEISFELD L B;LITTLE J R;WOLSTENHOLME W E .Bonding in urethane elastomers[J].Journal of Polymer Science,1962,56(164):455-463. |
[8] | Qiu SJ;Gan XX;Gao C;Zheng XD;Yu HJ;Fan HQ .Hydrogen bond effect of azido polyurethane elastomer by dynamic mechanical analysis[J].Journal of Polymer Science, Part B. Polymer Physics,2006(19):2841-2851. |
[9] | HAYEN H;NEFZGER H;EISENBACH C D .Structure and deformation behaviour of model poly(ether-urethane) elastomers[J].Macromolecular Chemistry and Physics,1994,195(08):2855-2873. |
[10] | Madhavan K;Reddy BSR .Synthesis and characterization of poly (dimethylsiloxane-urethane) elastomers: Effect of hard segments of polyurethane on morphological and mechanical properties[J].Journal of Polymer Science, Part A. Polymer Chemistry,2006(9):2980-2989. |
[11] | Energetic Studies on Epoxy-Polyurethane Interpenetrating Polymer NAetworks[J].Journal of Applied Polymer Science,2001(3):775-780. |
[12] | Jena KK;Chattopadhyay DK;Raju KVSN .Synthesis and characterization of hyperbranched polyurethane-urea coatings[J].European Polymer Journal,2007(5):1825-1837. |
[13] | Joe-Lahai Sormana;J.Carson Meredith .High-Throughput Discovery of Structure-Mechanical Property Relationships for Segmented Poly(urethane-urea)s[J].Macromolecules,2004(6):2186-2195. |
[14] | Lemon MT;Jones MS;Stansbury JW .Hydrogen bonding interactions in methacrylate monomers and polymers.[J].Journal of biomedical materials research, Part A,2007(3):734-746. |
[15] | R. Consiglio;N. X. Randall;B. Bellaton;J. Von Stebut .The nano-scratch tester(NST) as a new tool for assessing the strength of ultrathin hard coatings and the mar resistance of polymer films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1998(1/2):151-156. |
[16] | ULRICH ZORLL.Coating properties measure and control[M].Hannover:Vincentz Network,2003 |
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