以双酚A型环氧树脂紫外光阳离子固化体系为对象,系统研究了光引发剂和各种单体组成对光固化速度及固化膜机械物理性质的影响.结果表明,光引发剂的种类不但可以有效地影响光固化速度,还能对涂层硬度产生影响;环氧稀释剂在降低体系黏度的同时,对光固化速度和硬度产生负面影响;而羟基化合物对光固化速度几乎不产生影响,但是可以大幅度提高涂层的硬度和柔韧性;三元体系中,由于存在加合作用,在光固化速度和物理机械性质两方面都得到了很好的结果.这就使得能够根据具体要求,配制出各种性能都较好的材料,将大大扩展阳离子紫外光固化技术的应用领域.
参考文献
[1] | FOUASSIER JP.Photoinitiator[A].Munich,1995 |
[2] | DECKER C.Photoinitiated crosslinking polymerization[J].Progress In Polymer Science,1996(21):593-650. |
[3] | Decker C. .Kinetic study and new applications of UV radiation curing [Review][J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2002(18):1067-1093. |
[4] | Ewa Andrzejewska .Photopolymerization kinetics of multifunctional monomers[J].Progress in Polymer Science,2001(4):605-665. |
[5] | DECKER C.The Use of irradiation in UV polymerization[J].Polymer International,1998(45):133-141. |
[6] | 陈用烈;曾兆华;杨建文.辐射固化材料及其应用[M].北京:化学工业出版社,2003 |
[7] | 金养智.持续快速发展的中国光固化产业[J].精细与专用化学品,2004(20):3-6. |
[8] | 杨永源,吴玉民,胡辉,谭昊涯.辐射固化材料的现状和某些进展[J].感光科学与光化学,2002(03):230-238. |
[9] | 洪啸吟,金有铠,金养智.中国辐射固化技术发展[J].热固性树脂,2002(01):31-34. |
[10] | Decker C.;Zahouily K. .Light-stabilization of polymeric materials by grafted UV-cured coatings[J].Journal of Polymer Science, Part A. Polymer Chemistry,1998(14):2571-2580. |
[11] | Czech Z .Development in the area of UV-crosslinkable solvent-based pressure-sensitive adhesives with excellent shrinkage resistance[J].European Polymer Journal,2004(9):2221-2227. |
[12] | Benson RS. .Use of radiation in biomaterials science[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2002(0):752-757. |
[13] | Norbert Moszner;Ulrich Salz .New developments of polymeric dental composites[J].Progress in Polymer Science,2001(4):535-576. |
[14] | Papilloud S.;Baudraz D. .Migration tests for substrates printed with UV ink systems in aqueous simulants[J].Progress in Organic Coatings: An International Review Journal,2002(2/3 special issue si):231-237. |
[15] | 刘安昌,莫健华,黄树槐.阳离子光引发剂芳茂铁六氟磷酸盐的制备[J].感光科学与光化学,2004(03):234-237. |
[16] | 杨永源.[A].威海,2000 |
[17] | CRIVELLO JAMES V.;LIU SAOSHI .Photoinitiated Cationic Polymerization of Epoxy Alcohol Monomers[J].Journal of Polymer Science, Part A. Polymer Chemistry,2000(3):389-401. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%