以十二烷基苯磺酸(DBSA)掺杂的聚苯胺(PANI)为导电组分,三氯甲烷为溶剂,采用溶液共混法制备聚苯胺/丙烯酸酯共聚物(AA)导电薄膜.对导电薄膜进行了导电性能测试,扫描电镜(SEM)、红外光谱(FT-IR)及差示扫描量热(DSC)分析.结果表明:导电薄膜的电导率随PANI-DBSA含量的增加而增加,体系的逾渗阈值低于4%(质量分数).共混体系表现出良好的相容性.
参考文献
| [1] | CAO Y;SMITH P;HEEGAR A J .Processable forms of electrically conductive polyaniline[P].US 714165,1991-06-12. |
| [2] | 范俊华;万梅香;朱道本.可溶性导电聚苯胺的研究进展[J].高分子通报,1997(01):22-28. |
| [3] | Goh SH.;Ong CH.;Chan HSO. .MISCIBILITY OF POLYANILINE/POLY(VINYL ACETATE) BLENDS[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(13):2675-2679. |
| [4] | 潘玮,杨胜林,李光,江建明.PANI-DBSA/PAN导电薄膜的结构与性能[J].高分子材料科学与工程,2004(06):150-152,156. |
| [5] | 刘丹丹,宁平,夏林,王爱东,李红敏.导电聚苯胺/EAA共混物的导电性能研究[J].中国塑料,2005(02):45-47. |
| [6] | Abraham D.;Subramanyam SV.;Bharathi A. .HIGHLY CONDUCTING POLYMER BLEND FILMS OF POLYANILINE AND NYLON 6 BY COSOLVATION IN AN ORGANIC ACID[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(23):5295-5299. |
| [7] | Yamada K.;Yamane H.;Haishi T.;Yamamoto K.;Haraguchi T.;Kajiyama T. .Relations between molecular mixing state and conductive property in blends composed of polyaniline and aliphatic copolymer having acid groups[J].Journal of Applied Polymer Science,2002(5):1113-1117. |
| [8] | Moon HS.;Park JK. .Structural effect of polymeric acid dopants on the characteristics of doped polyaniline composites: Effect of hydrogen bonding[J].Journal of Polymer Science, Part A. Polymer Chemistry,1998(9):1431-1439. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%