以硝基芴和丙烯酸脂为原料,在碱性条件下,微波辐射(500 W)反应4～5 min,非常方便地合成了系列未见文献报道的Michael加成产物,该方法操作简单、产率较高(79％ ～ 87％).其结构经IR、1H NMR、MS和元素分析进行表征,并利用X射线单晶衍射分析法测定了化合物3b的单晶结构.
参考文献
| [1] | Wu W S,Inbasekaran M,Hudack M,et al.Recent Development of Polyfluorene-based RGB Materials for Light Emitting Diodes[J].Microelectron,2004,35(4):343-348. |
| [2] | Feng F.Solvent-free Michale Addition Reaction of Fluorene with Chalcon[J].Chinese Chem Lett,2011,22(1):29-32. |
| [3] | HU Weibing,FENG Fu,LI Yunpan,et al.Microwave-assisted Knoevenagel Reaction of 2-Nitrofluorene with Aromatic Aldehyde[J].Chinese J Org Chem,2011,31(6):897-900(in Chinese).胡卫兵,冯驸,黎云攀,等.微波辐射下2-硝基芴与芳香醛的Knoevenagel反应[J].有机化学,2011,31(6):897-900. |
| [4] | Han M,Lee S,Jung J,et al.Effect of a Perfluoroeyclopentene Core Unit on the Structures and Photoluminescence of Fluorene-and Anthracene-based Compounds[J].Tetrahedron,2006,62:9769-9775. |
| [5] | Wu C C,Liu T L,Huang W Y,et al.Unusual Nondispersive Ambipolar Carrier Transport and High Electron Mobility in Amorphous Ter(9,9-di-aryfluorene) s[J].J Am Chem Soc,2003,125(13):3710-3711. |
| [6] | Lou S L,Yu J S,Jiang Y D,etal.Influences of Fluorine Auxochrome in Fluorine Molecular Electroluminescent Material Onoptoelectronic Property[J].Chinese Sci Bull,2008,53 (19):2940-2945. |
| [7] | BAI Yinjuan,ZHAO Shuixia,CHEN Xudong,et al.Synthesis of 4-Arylideneamino-1,2,4-Triazoles under Microwave Irradiation[J].Chinese J Appl Chem,2008,25 (3):366-368 (in Chinese).白银娟,赵水侠,陈旭东,等.微波促进下4-芳基亚氨基-1,2,4-三唑的合成[J].应用化学,2008,25(3):366-368. |
| [8] | Qing H L.Microwave-assisted Synthesis of Asymmetric Thiocarbonohydrazones under Solvent-free Conditions[J].Chinese Chem Lett,2009,20(11):793-796. |
| [9] | FENG Fu,HU Weibing,LIU Hongxia,et al.Synthesis and Antibacterial of Some Schiff Bases Containing 2-Aminofluorene[J].Chinese J Appl Chem,2008,25(8):980-982(in Chinese).冯驸,胡卫兵,刘红霞,等.2-氨基芴席夫碱的合成及抗菌活性[J].应用化学,2008,25 (8):980-982. |
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