欢迎登录材料期刊网

材料期刊网

高级检索

合成了一种环境友好型的缓蚀剂——二硫代氨基甲酸改性葡萄糖(DTCG).采用该缓蚀剂在铜表面制备了自组装膜,并运用电化学阻抗谱、极化曲线方法研究了该膜在3% NaCl溶液中对铜的缓蚀性能.研究结果表明,DTCG自组装膜对铜有良好的缓蚀效果,在自组装时间为4h、自组装浓度为120 mg/L的缓蚀效率接近于97%.量子化学计算结果也证明了DTCG具有优异的缓蚀性能.

参考文献

[1] Aljinovic(a)a L J,Gudic(a) S,Mith M S (I).Inhibition of CuNi10Fe Corrosion in Seawater by Sodium-diethyl-dithiocarbamate:An Electrochemical and Analytical Study[J].J Appl Electrochem,2000,30:973-979.
[2] Liao Q Q,Yue Z W,Li Y J,et al.Inhibition of Brass Corrosion in 3% NaCl Solution by Sodium Diethyldithiocarbamate[J].Corrosion,2010,66(12):125002-1-6.
[3] Aiman E Al-Rawajfeh,Ehab M Al-Shamaileh.Inhibition of Corrosion in Steel Water Pipes by Ammonium Pyrrolidine Dithiocarbamate(APDTC)[J].Desalination,2007,206(1-3,5):169-178.
[4] JIANG Hong.The Test and Discussion on Using Copper Inhibitor APDC as a Substitute for MBT[J].Ind Water Treat,1998,18 (3):15-17 (in Chinese).江红.用APDC代替MBT铜缓蚀剂的试验与讨论[J].工业水处理,1998,18(3):15-17.
[5] Fan H B,Wang H L,Guo X P,et al.Corrosion Inhibition Mechanism of Carbon Steel by Sodium N,N-Diethyl Dithiocarbamate in Hydrochloric Acid Solution[J].Anti-Corros Methods Mater,2002,49(4):270-276.
[6] Fan H B,Fu C Y,Wang H L,et al.Inhibition of Corrosion of Mild Steel by Sodium N,N-Diethyl Dithiocarbamate in Hydrochloric Acid Solution[J].Br Corros J,2002,37(2):122-125.
[7] FAN Hongbo,HU Yongyou,ZHENG Jiashen.Inhibiting Mechanism of Sodium Dithiocarbamate to the Corrosion of Mild Steel in Sulfuric Acid[J].J South China Univ Technol(Nat Sci Edn),2005,33(6):55-58(in Chinese).范洪波,胡勇有,郑家燊.硫酸介质中二硫代氨基甲酸钠对碳钢的缓蚀机理[J].华南理工大学学报(自然科学版),2005,33(6):55-58.
[8] Liao Q Q,Yue Z W,Yang D,et al.Inhibition of Copper Corrosion in Sodium Chloride Solution by the Self-assembled Monolayer of Sodium Diethyldithiocarbamate[J].Corros Sci,2011,53 (5):1999-2005.
[9] Liao Q Q,Yue Z W,Yang D,et al.Self-assembled Monolayer of Ammonium Pyrrolidine Dithiocarbamate on Copper Detected Using Electrochemical Methods,Surface Enhanced Raman Scattering and Quantum Chemistry Calculations[J].Thin Solid Films,2011,519(19):6492-6498.
[10] JIANG Min,LI Yongmei,GU Guowei.Study on Toxicity of Nitrogenous Heterocyclic Compounds to Aquatic Organisms[J].Acta Sci Circum,2005,25(9):1253-1258((in Chinese).江敏,李咏梅,顾国维.含氮杂环化合物对水生生物的毒性作用研究[J].环境科学学报,2005,25(9):1253-1258.
[11] LIAO Qiangqiang,LI Yijiu,XIANG Bo,et al.Synthesis of a Modified Dithiocarbamate Glucose[J].Synth Chem,2010,18 (5):582-585 (in Chinese).廖强强,李义久,相波,等.二硫代氨基甲酸改性葡萄糖的合成[J].合成化学,2010,18(5):582-585.
[12] YIN Renhe,WAN Zongyue,XU Qunjie,et al.Study of Self-assembled Monolayer of Plant Acid for B30 Corrosion and Inhibiting Mechanism[J].Funct Mater,2007,38(4):562-564,572(in Chinese).印仁和,万宗跃,徐群杰,等.植酸自组装单分子膜对白铜B30缓蚀作用的研究[J].功能材料,2007,38(4):562-564,572.
[13] LI Ying,LIN Haichao,CAO Chunan.Relationship Between the Existing Form and Inhibiting Behavior of DDA on Inhibiting Interface[J].Acta Phys Chim Sin,1998,14(8):719-724(in Chinese).李瑛,林海潮,曹楚南.DDA在碱酸介质中的存在状态与缓蚀行为的关系[J].物理化学学报,1998,14(8):719-724.
[14] ZHANG Daquan,GAO Lixin,WANG Zhien.Study of Inhibition Effects of 2-n-Undecylimidazole on Copper in 3% NaCl Solution[J].J Chinese Soc Corros Prot,2002,22(4):237-240(in Chinese).张大全,高立新,汪知恩.NaCl溶液中烷基咪唑对铜的缓蚀作用研究[J].中国腐蚀与防护学报,2002,22(4):237-240.
[15] Zhang D Q,He X M,Cai Q,et al.Arginine Self-assembled Monolayers Against Copper Corrosion and Synergistic Effect of Iodide Ion[J].J Appl Electrochem,2009,39(8):1193-1198.
[16] Khaled K F.Guanidine Derivative as a New Corrosion Inhibitor for Copper in 3% NaCl Solution[J].Mater Chem Phys,2008,112(1):104-111.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%