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用酸性硫脲溶液萃取乙炔氢氯化失活催化剂中的铂离子,得到最佳回收的工艺参数,当萃取相比(A/O)为1,硫脲浓度为0.2 mol/L,盐酸浓度为0.5~0.6 mol/L时,萃取率达到98%以上;萃取后的有机相性质无改变,可重复使用,一次萃取后合成催化剂可使乙炔转化率达70%以上.

参考文献

[1] LUO Qin,YANG Qin,JIANG Wenwei,et al.A Process for the Co-Synthesis of Vinyl Chloride Monomer and Sodium Carbonate-the Hydrochlorination of Acetylene in Homogeneous Nonmercuric Catalysis[J].Sichuan Chem Ind,2007,10(5):20-23 (in Chinese).罗芩,杨琴,蒋文伟,等.乙炔液相非汞氢氯化联产碳酸钠和氯乙烯单体[J].四川化工,2007,10(5):20-23.
[2] HUO Yupeng,LUO Qin,YANG Qin,et al.Catalytic Hydro-Chlorination of Acetylene:Analysis and Improvement of Non-Mercuric Homogenous System[J].Chem Ind Eng Prog,2009,28(7):1182-1186(in Chinese).霍玉朋,罗芩,杨琴,等.乙炔氢氯化反应液相非汞催化体系的分析及优化[J].化工进展,2009,28(7):1182-1186.
[3] JIANG Wenwei,HUO Yupeng,YANG Qin,et al.Research Progress in Mercury-Free Catalysts for Hydrochlorination of Acetylene[J].Polyvinyl Chloride,2009,37(9):1-4(in Chinese).蒋文伟,霍玉鹏,杨琴,等.乙炔氢氯化反应用无汞催化剂的研究进展[J].聚氯乙烯,2009,37(9):1-4
[4] QIN Gaofei,ZHOU Ying,LUO Qin,et al.Research in Mercury-Free Catalysts for Hydrochlorination of Acetylene[C]//The 32nid National Technical Conference of PVC.Kunming:National PVC Information Station,Polyvinyl Chloride,2010:189-193(in Chinese).秦高飞,周莹,罗芩,等.乙炔氢氯化反应均相非汞催化体系的催化机理及失活原因分析[C]//第32届全国聚氯乙烯行业技术年会.昆明:全国聚氯乙烯信息站,《聚氯乙烯》编辑部,2010:189-193.
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[6] WANG Yanli,HUANG Ying.The Development Status of Extraction of Gold by Thiourea[J].Hydrometall China,2005,24(1):1-4(in Chinese).王艳丽,黄英.硫脲提金技术发展现状[J].湿法冶金,2005,24(1):14.
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