以1-十二醇、1-十四醇、1-十六醇、1-十八醇、马来酸酐和乙二醇为主要原料,合成4种琥珀酸酯磺酸盐Gemini表面活性剂;借助红外光谱和核磁共振氢谱对所合成的化合物结构进行了表征.4种表面活性剂均具有较低的临界胶束浓度,较强的乳化性能以及较好的泡沫性能.进一步讨论了4种表面活性剂结构与性能的关系.
参考文献
[1] | ZHAO Jianxi.Significance of Investigation of Gemini Surfactants and Its Development Trends[J].Fine Spec Chem,2008,16(2):9-14(in Chinese).赵剑曦.Gemini表面活性剂的研究与发展方向[J].精细与专用化学品,2008,16(2):9-14. |
[2] | LI Chen,YANG Jiping,CHEN Gong.Synthesis of Novel Gemini Surfactant and Its Surface Activity[J].Appl Chem Ind,2007,36 (5):425-427 (in Chinese).李晨,杨继萍,陈功.磺酸型Gemini表面活性剂的合成及表面活性[J].应用化工,2007,36(5):425-427. |
[3] | JIANG Xiaoming,CHEN Xiaoge,XIE Tian.Synthesis and Flotation Property of Gemini Anionic Surfactants[J].Chinese J Appl Chem,2010,27(6):742-744(in Chinese).姜小明,陈晓阁,解田.双子型阴离子表面活性剂的合成及浮选性能[J].应用化学,2010,27(6):742-744. |
[4] | Raoul Zana.Dimeric (Gemini) Surfactants:Effect of the Spacer Group on the Addociation Behavior in Aqueous Solution[J].J Colloid Interface Sci,2002,248(2):203-220. |
[5] | Fredic M Menger,Vasily A Migulin.Synthesis and Properties of Multiarmed Gemini[J].J Org Chem,1996,64(24):8914-8921. |
[6] | WU Yue,YE Xingkai,YANG Xiangguang,et al.Heterogenization of Heteropolyacids A General Discussion on the Preparation of Supported Acid Catalysts[J].J Mol Catal,1996,10 (4):299-319 (in Chinese).吴越,叶兴凯,杨向光,等.杂多酸的固载化-关于制备负载型酸催化剂的一般原理[J].分子催化,1996,10(4):299-319. |
[7] | SY/T 5370-1999 The Method for Measurement of Surface Tension & Interfacial Tension[S],1999.表面及界面张力测定法[S],1999. |
[8] | MAO Peikun.Industry Analysis of Synthetic Detergent[M].Beijing:China Light Industry Press,1988:385-471 (in Chinese).毛培坤.合成洗涤剂工业分析[M]北京:中国轻工业出版社,1988:385-471. |
[9] | GB/T 7462-94 Surface Active Aqents-Measurement of Foaming Power-Modified Ross-Miles Method[S],1994.表面活性剂发泡性的测定改进Ross-Miles法[S],1994. |
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