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以烟草花叶病毒(TMV)为基本构建单元,研究了其在毛细管、载玻片-载玻片和柱透镜-硅片3种不同受限空间下的自组装行为.结果表明,由于接触线有规律、重复性的粘滑运动,在3种受限体系下TMV均可组装得到高度规整的条带结构.在毛细管内组装可得到垂直于管的长轴方向的有序条带.随接触线深入管中心,条带跨距(l)与带宽(w)均逐渐增大.在2个平行载玻片所构成的可控空间内所得到的条带以2条互相垂直的中心线为轴对称排列,并沿从载玻片边缘至轴向中心方向条带跨距和带宽梯度增大.同样,利用柱透镜-硅片所组成的体系可得到类似平行线状条带,其跨距、带宽及条带高度沿从外部边缘至柱透镜/硅片接触中心方向逐渐减小.在3种体系下,棒状TMV粒子均平行于接触线的方向取向.TMV浓度对组装结构具有显著影响,随着浓度的增加,条带跨距和带宽均增加,直至条带结构消失形成连续膜.

参考文献

[1] Picknett R G,Bexon R.The Evaporation of Sessile or Pendant Drops in Still Air[J].J Colloid Interface Sci,1977,61:336-350.
[2] Yu H Z,Soolaman D M,Rowe A W,et al.Evaporation of Water Microdroplets on Self-Assembled Monolayers:From Pinning to Shrinking[J].Chem Phys Chem,2004,5:1035-1038.
[3] Huang J X,Kim F,Tao A R,et al.Spontaneous Formation of Nanoparticle Stripe Patterns through Dewetting[J].Nat Mater,2005,4:896-900.
[4] Deegan R D,Bakajin O,Dupont T F,et al.Capillary Flow as The Cause of Ring Stains from Dried Liquid Drops[J].Nature,1997,389:827-829.
[5] Maheshwari S,Zhang L,Zhu Y X,et al.Coupling between Precipitation and Contact-Line Dynamics:Multiring Stains and Stick-Slip Motion[J].Phys Rev Lett,2008,100:044503.
[6] Shmuylovich L,Shen A Q,Stone H A.Surface Morphology of Drying Latex Films:Multiple Ring Formation[J].Langmuir,2002,18:3441-3445.
[7] Byun M,Laskowski R L,He M,et al.Controlled Evaporative Self-Assembly of Hierarchically Structured Regioregular Conjugated Polymers[J].Soft Matter,2009,5:1583-1586.
[8] Xu J,Xia J F,Hong S W,et al.Self-Assembly of Gradient Concentric Rings via Solvent Evaporation from a Capillary Bridge[J].Phys Rev Lett,2006,96:066104.
[9] Xu J,Xia J F,Lin Z Q.Evaporation-Induced Self-Assembly of Nanoparticles from a Sphere-on-Flat Geometry[J].Angew Chem Int Ed,2007,46:1860-1863.
[10] Lin Y,Su Z H,Xiao G H,et al.Self-Assembly of Virus Particles on Flat Surfaces via Controlled Evaporation[J].Langmuir,2011,27:1398-1402.
[11] Lin Y,Balizan E,Lee L A,et al.Self-Assembly of Rodlike Bio-Nanoparticles in Capillary Tubes[J].Angew Chem Int Ed,2010,49:868-872.
[12] Nam K T,Kim D W,Yoo P J,et al.Virus-Enabled Synthesis and Assembly of Nanowires for Lithium Ion Battery Electrodes[J].Science,2006,312:885-888.
[13] Rong J H,Lee L A,Li K,et al.Oriented Cell Growth on Self-Assembled Bacteriophage M13 Thin Films[J].Chem Commun,2008,41:5185-5187.
[14] He J B,Niu Z W,Tangirala R,et al.Self-Assembly of Tobacco Mosaic Virus at OiL/Water Interfaces[J].Langmuir,2009,25:4979-4987.
[15] Lin Y,Su Z H,Balizan E,et al.Controlled Assembly of Protein in Glass Capillary[J].Langmuir,2010,26:12803-12809.
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