探究了游离脂肪酶NS81006催化油脂甲(乙)醇解制备生物柴油的反应历程,并对该体系进行了酶促反应动力学研究.结果表明,催化过程中油脂同时存在酯交换及先水解再酯化两种反应历程.在以甲醇或乙醇作为酰基受体的反应过程中,酯交换反应速率明显大于水解反应速率.进一步研究表明,油脂甲醇解反应速率常数大于乙醇解,揭示了以甲醇或乙醇为不同酰基受体时反应速率存在差异的主要原因在于乙醇解反应的酯交换过程较慢.
参考文献
| [1] | Wardle D A .[J].Renewable & Sustainable Energy Reviews,2003,7:1. |
| [2] | Balat M;Balat H .[J].Applied Energy,2010,87:1815. |
| [3] | Lü D;Du W;Zhang G L;Liu D H .[J].Process Biochemistry,2010,45:446. |
| [4] | Sun T;Du W;Zeng J;Dai L M Liu D H .[J].Process Biochemistry,2010,45:514. |
| [5] | Bajaj A;Lohan P;Jha P N;Mehrotra R .[J].Journal of Molecular Catalysis B:Enzymatic,2010,62:9. |
| [6] | Li N W;Zong M H;Wu H .[J].Process Biochemistry,2009,44:685. |
| [7] | Cheirsilp B;H-Kittikun A;Limkatanyu S .[J].Biochemical Engineering Journal,2008,42:261. |
| [8] | Chen X;Du W;Liu D H .[J].Biochemical Engineering Journal,2008,40:423. |
| [9] | Du W;Xu Y Y;Liu D H;Zeng J .[J].Journal of Molecular Catalysis B:Enzymatic,2004,30:125. |
| [10] | Chen X;Du W;Liu D H .[J].World Journal of Microbiology and Biotechnology,2008,24:2097. |
| [11] | Ren H J;Du W;Lü L L;Liu D H .[J].Journal of the American Oil Chemists'society,2011,88:1551. |
| [12] | Du W;Wang L;Liu DH .Improved methanol tolerance during Novozym435-mediated methanolysis of SODD for biodiesel production[J].Green chemistry,2007(2):173-176. |
| [13] | Du W;Li W;Sun T;Chen X Liu D H .[J].Appl Microbiol Bio-technol,2008,79:331. |
| [14] | Wang, Y;Wu, H;Zong, MH .Improvement of biodiesel production by lipozyme TL IM-catalyzed methanolysis using response surface methodology and acyl migration enhancer[J].Bioresource Technology,2008(15):7232-7237. |
| [15] | Chen X;Du W;Liu D H;Ding F X .[J].J Chem Technol Biotech-nol,2008,83:71. |
| [16] | 陈和,王金福.强碱催化棉籽油酯交换制备生物柴油的动力学[J].化工学报,2005(10):1971-1974. |
| [17] | Kaieda M;Samukawa T;Matsumoto T;Ban K Kondo A Shimada Y Noda H Nomoto F Ohtsuka K Izumoto E Fu-kuda H .[J].Journal of Bioscience and Bioengineering,1999,88:627. |
| [18] | 苏正定;姚汝华 .生物化学杂志(Su Zh D,Yao R H[J].Bio-chem J),1993,9:42. |
| [19] | Li W;Li R W;Li Q;Du W Liu D H .[J].Process Biochemistry,2010,45:1888. |
| [20] | Joshi H;Toler J;Moser B R;Walker T .[J].Eur J Lipid Sci Tech-nol,2009,111:464. |
| [21] | Moreira A B R;Perez V H;Zanin G M;de Castro H F .[J].Energy and Fuels,2007,21:3689. |
| [22] | Issariyakul T;Kulkarni M G;Dalai A K;Bakhshi N N .[J].Fuel Processing Technology,2007,88:429. |
| [23] | Zhou W Y;Konar S K;Boocock D G B .[J].Journal of the American Oil Chemists'society,2003,80:367. |
| [24] | Rosset I G;Tavares M C H;Assaf E M;Porto A L M .[J].Applied Catalysis A:General,2011,392:136. |
| [25] | Tongboriboon K;Cheirsilp B;H-Kittikun A .[J].Journal of Molecular Catalysis B:Enzymatic,2010,67:52. |
| [26] | Rosa C D;Morandim M B;Ninow J L;Oliveira D Treichel H Oliveira J V .[J].Bioresource Technology,2009,100:5818. |
| [27] | Lee K T;Akoh C C .[J].Food Review,1998,14:17. |
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