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以共沉淀法制各了磺基水杨酸插层Mg/Cu/Zn/Al-LDHs复合材料,借助XRD、FT-IR、TG-DTA等手段对样品测试表明,客体进入LDHs层间,层间距由0.832 nm扩至1.125 nm,推测了层间排列模型;EDS分析验证了插层后层板元素组成比接近理论比值,插层组装仍能保持良好的层状结构,且客体进入层间因静电和氢键等作用提高了热稳定性;同时由UV-DRS结果可知,插层LDHs复合材料对紫外线具有良好的屏蔽和吸收双重作用.

参考文献

[1] NEADES R,COX L,PELLING J C.S-pHase arrest in mousekeratinocytes exposed to multiple dosea of ultraviolet B/A radiation.Mol.Carcinog.,1998,23(3):159-167.
[2] GASPARRO F P.Sunscreens,skin photobiology,and skin cancer:the need for UVA protectionand evaluation of efficacy.Environ Health Perspect.,2000,108(1):71-88.
[3] KLOPROGGE J T,FROST R L.Infrared emission spectroscopic study of the thermal transformation of Mg,Ni and Co hydrotalcite catalysts.Appl.Catal.,1999,184(1):61-71.
[4] CONSTANTINO V R L,PINNAVAIA T J.Basic properties of Mg2+1-xAl3+x layered double hydroxides intercalated by carbonate,hydroxide,chloride and sulfate anions.Inorg.Chem.,1995,34(4):883-892.
[5] KOOLI F,KOSUGE K,HIBINO T,et al.Synthesis and properties of Mg-Zn-Al-SO4 hydrotalcite-like compounds,J.Mater Sci.,1993,28(10):2769-2773.
[6] ROUSSELOT I,TAVIOT-GU(E)HO C,BESSE J P.Synthesis and characterization of mixed Ga/Al-containing layered double hydroxides:study of their basic properties through the Knoevenagel condensation of benzaldehyde and ethyl cyanoacetate,and comparison to other LDHs.Int.J.Inorg.Mater.,1999,1(2):165-174.
[7] MARGARITA A,SONIA Q,CRISTINA M,et al.Synthesis and characterization of layered double hydroxides(LDH) intercalated with non-steroidal anti-inammatory drugs(NSAiD).J.Solid State Chem.,2004,11(177):3954-3962.
[8] MOUSTY C,MARTELET C,JAFFREZIC-RENAULT N.Urea biosensors based on immobilization of urease into two oppositely charged clays(laponite and Zn-Al layered double hydroxides).Anal.Chem.,2002,74(16):4037-4043.
[9] WANG LIANG,MENG XIANG-JU,XIAO FENG-SHOU.Au nanoparticles supported on a layered double hydroxide with excellent catalytic properties for the aerobic oxidation of alcohols.Chinese Journal of Catalysis,2010,31(8):943-947.
[10] WANG JUN,LIU YAN-FENG,LIU QI,et al.Studies on the preparation and electrochemical performance of Ni/Al hydrotalcite with high crystallinty.Chemical Research and Application.,2010,22(3):379-383.
[11] ZHAO CE,ZENG HONG-YAN,WANG YA-JU,et al."Memory effect" of Mg-Al hydrotalcites and its chromium(Ⅵ) adsorption property.Journal of Inorganic Materials.,2011,26(8):874-880.
[12] NI ZHE-MING,XIA SHENG-JIE,WANG LI-GENG,et al.Supramolecular structure,thermal stability and release property of new drug-inorganic composites norfloxacin-intercalated Mg-Al-layered double hydroxides.Chemical Journal of Chinese Universities,2007,28(7):1214-1219.
[13] REN LING-LING,HE JING,EVANS DAVID G,et al.Intercalation and assembly of supramolecular materials of glutamic acid pillared layered double hydroxides.Chemical Research In Chinese Universities,2003,24(1):169-173.
[14] ZHANG WEI-FENG,LI DIAN-QING,SUN MENG,et al.Supramolecular assembly of methyl orange-pillared hydrotalcite and its light and thermal stability.Chemical Research In Chinese Universities,2004,25(10):1799-1803.
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