利用浓硫酸、高锰酸钾等强氧化剂制备了氧化石墨,将其与钛酸钡和环氧树脂复合,制备了三相复合材料.研究了氧化石墨的添加量对于复合材料介电性能的影响.结果发现在氧化石墨的添加量很少时,三相复合材料的介电常数显著地高于钛酸钡/环氧树脂两相复合材料,同时介电损耗仍然维持在较低的水平.钛酸钡/环氧树脂的介电常数为17.7 (20℃,1 kHz),当加入3wt%氧化石墨,介电常数增加到42.6,介电损耗为0.043.因此该三相复合材料适合用于埋入式电容器的介质材料.最后初步探讨了氧化石墨对复合材料介电性能的影响机理.
参考文献
[1] | Ostmarn A,Neumann A,Reichl H.Ultra-high Density Packaging by Component Integration,26th ISSE.Stará Lesná,Slovak Republic,2003:493-498. |
[2] | Lai Q,Lee B I,Chen S H,et al.High-dielectric-constant silverepoxy composites as embedded dielectrics.Adv.Mater.,2005,17(14):1777-1781. |
[3] | Grannan D M,Garland J C,Tanner D B.Critical behavior of the dielectric constant of a random composite near the percolation threshold.Phys.Rev.Lett.,1981,46(5):375-378. |
[4] | Xu J,Wong C P.Low loss percolative dielectric composite.Appl.Phys.Lett.,2005,87(8):082907. |
[5] | Lu J,Moon K S,Xu J,et al.Synthesis and dielectric properties of novel high k polymer composites containing in-situ formed silver nanoparticles for embedded capacitor applications.J.Mater.Chem.,2006,16:1543-1548. |
[6] | Dang Z M,Shen Y,Nan C W.Dielectric behavior of three-phase percolative Ni-BaTiO3/Polyvinylidene fluoride composites.Appl.Phys.Lett.,2002,81(25):4814-4816. |
[7] | Choi H W,Heo Y W,Lee J H,et al.Effects of BaTiO3 on dielectric behavior of BaTiO3-Ni-polymethylmethacrylate composites.Appl.Phys.Lett.,2006,89(13):132910-1-3. |
[8] | Dang Z M,Fan L Z,Shen Y,et al.Study on dielectric behavior of a three-phase CF/(PVDF + BaTiO3) composite.Chem.Phy.Lett.,2003,369(1/2):95-100. |
[9] | Yao S H,Dang Z M,Jiang M J,et al.BaTiO3-carbon nanotube/polyvinylidene fluoride three-phase composites with high dielectric constant and low dielectric loss.Appl.Phys.Lett.,2008,93(18):182905-1-3. |
[10] | Geim A K.Graphene:status and prospects.Science,2009,324(5934):1530-1534. |
[11] | SUN Yufeng,LIU Shaobo,LI Huihua,et al.Synthesis of graphene oxide and its gas sensing properties to NH3.Journal of Functional Materials,2012,6(43):712-714. |
[12] | Loh K P,Bao Q L,Eda G; et al.Graphene oxide as a chemically tunable platform for optical applications.Nature Chemistry,2010,2:1015-1024. |
[13] | YE Jiankun,WANG Gengchao,YAO Bin,et al.Effect of content of poly(aniline-co-o-anisidine) on structure and properties of intercalated graphite oxide composites.Journal of Inorganic Materials,2008,23(5):945-949. |
[14] | Kou S W,Yu S H,Sun R,et al.High-dielectric-constant Graphite Oxide-polyimide Composites as Embedded Dielectrics,IMPACT.Taipei,Taiwan,China,2012:86-89. |
[15] | Hummers W S,Offeman R E.Preparation of graphite oxide.J.Am.Chem.Soc.,1958,80(6):1339. |
[16] | Wang G X,Yang J,Park J,et al.Facile synthesis and characterization of graphene nanosheets.J.Phys.Chem.C,2008,112(22):8192-8195. |
[17] | Tsangaris G M,Psarras G C,Kouloumbi N.Electric modulus and interfacial polarization in composite polymeric systems.Journal of Materials Science,1998,33(8):2027-2037. |
[18] | 孙目珍.电介质物理基础.广州,华南理工大学出版社.2000:97-121. |
[19] | Yang W H,Yu S H,Sun R,et al.Electrical modulus analysis on the Ni/CCTO/PVDF system near the percolation threshold.J.Phys.D:Appl.Phys.,2011,44(47):475305-1-3. |
[20] | Shehzad K,Dang Z M,Ahmad M N,et al.Effects of carbon nanotubes aspect ratio on the qualitative and quantitative aspects of frequency response of electrical conductivity and dielectric permittivity in the carbon nanotube/polymer composites.Carbon,2013,54:105-112. |
[21] | Xu H P,Dang Z M,Bing N C,et al.Temperature dependence of electric and dielectric behaviors of Ni/polyvinylidene fluoride composites.Journal of Applied Physics,2010,107(3):034105 1-5. |
[22] | Lee D W,Seo J W,Jelbert G R,et al.Transparent and flexible polymerized graphite oxide thin film with frequency-dependent dielectric constant.Appl.Phys.Lett.,2009,95(17):172901-1-3. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%