采用简单的离子交换沉积法制备了SnS敏化的纳晶TiO2光阳极.通过SEM、XRD、UV-Vis等手段对光阳极的表面形貌,晶态结构,紫外-可见吸收和散射性能进行表征.并分别以聚苯胺和铂为催化剂制备对电极,以含碘氧化还原电对和硫氧化还原电对溶液为电解质,组装SnS敏化太阳能电池,对其光电性能进行研究.通过比较不同光阳极、电解质和对电极的组合,发现用光阳极为离子交换沉积9次SnS的纳晶TiO2膜,对电极为聚苯胺不锈钢网压片膜,电解质为含硫氧化还原电对溶液组装的太阳能电池光电性能最佳,其短路电流、开路电压、填充因子和光电转换效率分别达到4.59 mA/cm2、0.547 V、0.505和1.27%.
参考文献
[1] | Dittrich T,Belaidi A,Ennaoui A,et al.Concepts of inorganic solid-state nanostructured solar ceils.Sol.Energy Mater Sol.Cells,2011,95(6):1527-1536. |
[2] | ZHOU Feng-Ling,LI Xiao-Min,GAO Xiang-Dong,et al.Low cost preparation and photoelectric property study of PbSe nanocrystalline films.Journal of Inorganic Materials,2009,24(4):778-782. |
[3] | Guang Z,Tao X,Tian L,et al.Graphene-incorporated nanocrystalline TiO2 films for CdS quantum dot-sensitized solar cells.J.Electroanal.Chem.,2011,650(2):248-251. |
[4] | Lee H J,Wang M K,Chen P.Efficient CdSe quantum dot-sensitized solar cells prepared by an improved successive ionic layer adsorption and reaction process.Nano Lett.,2009,9(12):4221-4227. |
[5] | Hyun B R,Bartnik A C,Lee J K,et al.Role of solvent dielectric properties on charge transfer from PbS nanocrystals to molecules.Nano Lett.,2010,10(1):318-323. |
[6] | Choi J J,Lim Y F,Santiago-Berrios M E B,et al.PbSe nanocrystal excitonic solar cells.Nano Lett.,2009,9(11):3749-3755. |
[7] | Messina S,Nair M T S,Nair P K.Solar cells with Sb2S3 absorber films.Thin Solid Films,2009,517(7):2503-2507. |
[8] | Robert W,Ogah E.Thermally evaporated thin films of SnS for application in solar cell devices.Thin Solid Film,2009,517(7):4702-4705. |
[9] | Vequizo J J M,Ichimura M.Fabrication of electrodeposited SnS/SnO2 heterojunction solar cells.J.Appl.Phys.,2012,51(10):381-384. |
[10] | Bashkirov S A,Gremenok V F,Ivanov V A,et al.Tin sulfide thin films and Mo/p-SnS/n-CdS/ZnO heterojunctions for photovoltaic applications.Thin Solid Films,2012,520(17):5807-5810. |
[11] | Guo W,Shen Y H,Wu M X,et al.Highly efficient inorganicorganic heterojuction solar cells based on SnS-sensitized spherical TiO2 electrodes.Chem.Commun.,2012,48:6133-6135. |
[12] | Guo W,Shen Y H,Wu M X,et al.SnS-quantum dot solar cells using novel TiC counter electrode and organic redox couples.Chem.Eur.J.,2012,18(25):7862-7868. |
[13] | Santra P K,Kamat P V.Mn-doped quantum dot sensitized solar cells:a strategy to boost efficiency over 5%.J.Am.Chem.Soc.,2012,134(5):2508-2511. |
[14] | Tsukigase H,Suzuki Y,Berger M H.Synthesis of SnS nanoparticles by SILAR method for quantum dot-sensitized solar cells.J.Nanosci.Nanotech.,2011,11(3):1914-1922. |
[15] | Murakami T,Gr(a)tzel M.Counter electrodes for DSC:application of functional materials as catalysts.Inorganica Chimica Acta,2008,361(3):572-580. |
[16] | Deepa K G,Nagaraju J.Growth and photovoltaic performance of SnS quantum dots.Mater.Sci.Eng.B,2012,177(13):1023-1028. |
[17] | Kamat P V.Boosting the efficiency of quantum dot sensitized solar cells through modulation of interfacial charge transfer.Acc.Chem.Res.,2012,45 (11):1906-1915. |
[18] | Shalom M,Buhbut S,Tirosh S,et al.Design rules for high-efficiency quantum-dot-sensitized solar cells:a multilayer approach.J.Phys.Chem.Lett.2012,3(17):2436-2441. |
[19] | Yang H,Fan W,Vaneski A,et al.Heterojunction engineering of CdTe and CdSe quantum dots on TiO2 nanotube arrays:intricate effects of size-dependency and interfacial contact on photoconversion efficiencies.Adv.Funct.Mater.,2012,22(13):2821-2829. |
[20] | Chang C H,Lee Y L.Efficient polysulfide electrolyte for CdS quantum dot-sensitized solar cells.J.Power Sources,2008,185(1):584-588. |
[21] | Tsao H N,Burschka J,Yi C,et al.Influence of the interfacial charge transfer resistance at the counter electrode in dye-sensitized solar cells employing cobalt redox shuttles.Energy Environ.Sci.2011,4:4921-4924. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%