以一氧化硅、蔗糖及天然石墨为原料,通过高能球磨和热解工艺制备了电化学性能优异的SiO/C/G复合负极材料.采用X射线衍射仪(XRD)和扫描电子显微镜(SEM)对复合材料的物相和形貌进行了表征.所制备的复合材料中,纳米SiO颗粒(<50 nm=被无定形碳粘结并均匀分散在石墨鳞片上.电化学性能测试表明,该复合材料100次循环后,可逆容量高达1108.9 mAh/g,容量保持率为103.8%.优异的电化学性能主要归因于纳米SiO颗粒在无定形碳基体中的均匀分布、无定形碳基体的缓冲作用和石墨相对复合材料导电性能的改善.
参考文献
[1] | Tarascon J M,Armand M.Issues and challenges facing rechargeable lithium batteries.Nature,2001,414:359-367. |
[2] | Li H,Wang Z X,Chen L Q,et al.Research on advanced materials for Li-ion batteries.Adv.Mater.,2009,219(45):4593-4607. |
[3] | Kim J H,Sohn H J,Kim H,et al.Enhanced cycle performance of SiO-C composite anode for lithium-ion batteries.J.Power Sources,2007,170(2):456-459. |
[4] | ZHANG Peng-Chang,YANG Xue-Lin,YU De-Xin,et al.Synthesis of silicon/carbon composite anode prepared by in-situ carbothermal reduction for lithium ion batteries.Chinese J.Inorg.Chem.,2011,27(5):898-902. |
[5] | Kim J H,Park C M,Kim H,et al.Electrochemical behavior of SiO anode for Li secondary batteries.J.Electroanal.Chem.,2011,661(1):245-249. |
[6] | Miyachi M,Yamamoto H,Kawai H,et al.Analysis of SiO anodes for lithium-ion batteries.J.Electrochem.Soc.,2005,152(10):A2089-A2091. |
[7] | Yang J,Takeda Y,Imanishi N,et al.SiOx-based anodes for secondary lithium batteries.Solid State Ionics,2002,152-153(12):125-129. |
[8] | Beaulieu L Y,Eberman K W,Turner R L,et al.Colossal reversible volume changes in lithium alloys.Electrochem.Solid-State Lett.,2001,4(9):137-140. |
[9] | Guo Z P,Wang J Z,Liu H K,et al.Study of silicon/polypyrrole composite as anode materials for Li-ion batteries.J.Power Sources,2005,146(1/2):448-451. |
[10] | Kim B C,Uono H,Satou T,et al.Cyclic properties of Si-Cu/carbon nanocomposite anodes for Li-ion secondary batteries.J.Electrochem.Soc.,2005,152(3):A523-A526. |
[11] | Morita T,Takami N.Nano Si cluster-SiOx-C composite material as high-capacity anode material for rechargeable lithium batteries.J.Electrochem.Soc.,2006,153(2):A425-A430. |
[12] | Doh C H,Park C W,Shin H M,et al.A new SiO/C anode composition for lithium-ion battery.J.Power Sources,2008,179(1):367-370. |
[13] | Guerfi A,Charest P,Dontigny M,et al.SiOx-graphite as negative for high energy Li-ion batteries.J.Power Sources,2011,196(13):5667-5673. |
[14] | Yang X L,Wen Z Y,Xu X X,et al.Nanosized silicon-based composite derived by in situ mechanochemical reduction for lithium ion batteries.J.Power Sources,2007,164(2):880-884. |
[15] | YANG Xue-Lin,ZHANG Lu-Lu,YOU Min,et al.Synthesis of Si/Sn binary lithium-storage host composite anode materials by in-situ mechanochemical reaction.Chinese J.Inorg.Chem.,2008,24(8):1320-1324. |
[16] | Zhang T,Gao J,Zhang H P,et al.Preparation and electrochemical properties of core-shell Si/SiO nanocomposite as anode material for lithium ion batteries.Electrochem.Commun.,2007,9(5):886-890. |
[17] | Hu Y S,Demir-Cakan R,Titirici M M,et al.Superior Storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-ion batteries.Angew.Chem.Int.Ed.,2008,47(9):1645-1649. |
[18] | Lee J I,Lee K T,Cho J,et al.Chemical-assisted thermal disproportionation of porous silicon monoxide into silicon-based multicomponent systems.Angew.Chem.,2012,124(11):2821-2825. |
[19] | Liu Y,Hanai K,Yang J,et al.Silicon/carbon composites as anode materials for Li-ion batteries.Electrochem.Solid-State Lett.,2004,7(10):A369-A372. |
[20] | Limthongkul P,Jang Y I,Dudney N J,et al.Electrochemically-driven solid-state amorphization in lithium-silicon alloys and implications for lithium storage.Acta Mater.,2003,51(4):1103-1113. |
[21] | Martinent A,Gorrec B L,Montella C,et al.Three-electrode button cell for EIS investigation of graphite electrode.J.Power Sources,2001,97-98(7):83-86. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%