欢迎登录材料期刊网

材料期刊网

高级检索

Mesoporous carbon CMK-3 was synthesized by using SBA-15 silica mesoporous as hard template and characterized through nitrogen adsorption/desorption and low angle X-ray diffraction. As-prepared material with large pores and high surface area was used to remove Orange G dye from aqueous solution. Adsorption experiments were carried out as batch studies at variety of contact times, pH, initial dye concentrations, temperatures and salt concentrations. Langmuir and Freundlich isotherm models were employed to simulate the equilibrium data of anionic dye. It was found that the equilibrium data were well represented by the Langmuir isotherm, yielding maximum monolayer adsorption capacity of 189 mg/g. Experimental data were analyzed using pseudo-first order and pseudo-second order kinetic models and obtained results indicated that kinetics followed a pseudo-second order equation.

Mesoporous carbon CMK-3 was synthesized by using SBA-15 silica mesoporous as hard template and characterized through nitrogen adsorption/desorption and low angle X-ray diffraction. As-prepared material with large pores and high surface area was used to remove Orange G dye from aqueous solution. Adsorption experiments were carried out as batch studies at variety of contact times, pH, initial dye concentrations, temperatures and salt concentrations. Langmuir and Freundlich isotherm models were employed to simulate the equilibrium data of anionic dye. It was found that the equilibrium data were well represented by the Langmuir isotherm, yielding maximum monolayer adsorption capacity of 189 mg/g. Experimental data were analyzed using pseudo-first order and pseudo-second order kinetic models and obtained results indicated that kinetics followed a pseudo-second order equation.

参考文献

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8] Zollinger H. Color Chemistry: Synthesis, Properties and Applications of Organic Dyes and Pigments. Wiley-VCH, Cambridge, 2003.

[2] Christie R M, Mather R R, Wardman R H. Chemistry of Colour Application. Wiley, Baackwell, United Kingdom, 1999.

[3] Karthikeyan J. Pollution management in industries. Environmental publication-Karda, India, 1988.

[4] Forgacs E, Cserhati T, Oros G. Removal of synthetic dyes from wastewaters: a review. Environment International, 2004, 30(7): 953-971.

[5] Allen S J. Use of adsorbents for the removal of pollutants from wastewaters: types of adsorbent materials. CRC, Boca Raton, 1996.

[6] McKay G. The adsorption of dyestuffs from aqueous solution using activated carbon: analytical solution for batch adsorption based on external mass transfer and pore diffusion. The Chemical Engineering Journal, 1983, 27(3): 187-196.

[7] Wang S, Li H. Kinetic modelling and mechanism of dye adsorption on unburned carbon. Dyes and Pigments, 2007, 72(3): 308-314.

[8] Tan I, Hameed B H, Ahmad A L. Equilibrium and kinetic studies on basic dye adsorption by oil palm fibre activated carbon. Chemical Engineering Journal, 2007, 127(1/2/3): 111-119.

[9] Iqbal M J, Ashiq M N. Adsorption of dyes from aqueous solutions on activated charcoal. J. Hazard. Mater., 2007, 139(1): 57-66.

[10] Meshko V, Markovska L, Mincheva M, et al. Adsorption of basic 
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%