通过把硅铝分子筛的骨架脱铝过程简化为分子筛骨架中杂原子的扩散和空位的形成及迁移过程,使用费克第二定律建立扩散方程,得到任意时刻铝原子的浓度关于位置的函数,并讨论了影响脱铝的几个重要因素.用XPS、红外光谱和27Al-NMR测定在一定条件下处理后的氢型丝光沸石和ZSM-5的骨架硅铝比的变化,并与由所建立的数学模型计算出的骨架硅铝比比较,验证了公式的准确性.
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