采用磁控溅射方法制备了Ti膜及TiMo、TiMoYAl和TiZrYAl等三种合金膜.合金膜中Mo、Zr和Al三种元素成份与靶材成分基本一致,而Y元素则与靶材成分有较大的偏差.在400℃吸氢工艺下,四种膜材的吸氢动力学性能良好,没有脱膜现象,饱和吸氢量均可超过1.5(H/M).膜材的吸氢PCT曲线表明,含Mo合金膜材具有最高的吸氢平衡压,外推出的室温下的数量级约为10-4Pa.
参考文献
[1] | C.R.Brune, R.W.Kavanagh, Phys. Res. A, 343, 415(1994) |
[2] | B.J.Hughey, Phys. Res. B, 95, 393(1995) |
[3] | WANG Longbao, LV Manqi, Li Yiyi, Acta Metallurgica Sinica, 39(5), 449(2003)(王隆保,吕曼祺,李依依,金属学报,39(5),449(2003)) |
[4] | L.C.Beavis, J. Less-Comm. Met., 27, 201(1972) |
[5] | D.L.Smith, Thin Film Deposition (New York: McGraw-Hill Inc. Press, 1995) p.86 |
[6] | H.Kanzaki, J. Phys. Chem. Solids, 2(1), 24(1957) |
[7] | Y.Y.Tse, D.Babonneau, Surf. Coat. Tech., 180, 470(2004) |
[8] | P.E.Irving, C.J.Beevers, Metall. Trans., 2, 613(1971) |
[9] | ZHENG Hua, LIU Shi, MA Aihua, WANG Longbao, Chinese Journal of Materials Research, 17(6), 590(2002)(郑华,刘实,马爱华,王隆保,材料研究学报,17(6),590(2002)) |
[10] | A.San Martin, F.D.Manchester, Bulletin of Alloy Phase Diagrams, 8(1), 30(1987) |
[11] | Z.S.Wronski, Inter. Mater. Res., 46(1), 1(2001) |
[12] | ZHAO Yue, ZHENG Hua, LIU Shi, WANG Longbao, Acta Metallurgica Sinica, 39(1), 89(2003)(赵越,郑华,刘实,王隆保,金属学报,39(1),89(2003)) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%