利用差热(扫描)分析、X射线、透射电镜、振动样品磁强计研究了添加Co、Dy对Fe3B/Nd2Fe14B纳米复合永磁材料的微结构和性能的影响结果表明:添加适当的微量元素可以提高Nd4 5Fe77B18.5纳米复合永磁材料的内禀磁性,改进微结构,从而提高材料的永磁性能.在Nd4 5Fe77B8.5中添加1%~3%(原子分数)的Co、Dy明显地降低材料的晶化温度和最佳热处理温度、提高了2:14:1相的居里温度、改善了纳米复合永磁材料的微观结构,从而提高材料的永磁性能.与Nd4.5Fe77B18.5相比,Nd3.5Fe74Co3Dy1B18.5的永磁性能为:Br=1.06 T,jHc=328 kA/m,(BH)max=108.9 kJ/m3,分别提高了26%,17%和104%.
参考文献
[1] | R.Skomski, J.M.D.Coey, IEEE Trans. on Mag., Nucleation field and energy product of aligned two-phase magnets-progress towards the ‘1MJ/m3 ' magnet. 29, 2860(1993) |
[2] | D.H. Ping, K.Hono, H.Kanekiyo, S.Hirosawa, J.ApphPhys, Mechanism of grain size refinement of Fe3B/Nd2Fe14B nanocomposite permanent magnet by Cu addition. 85, 2448(1999) |
[3] | C.J.Yang, E.B.Park, J.Magn. Magn.Mater., The effect of Co on the enhanced magnetic properties of Fe3B/Nd2Fe14B magnets. 212, 168(2000) |
[4] | George C. Hadjipanayis, J. Magn. Magn. Mater., Nanophase hard magnets. 200, 373(1999) |
[5] | Q.F.Xiao, T.Zhao, Z.D.Zhang, E.Bruck, K.H.J.Buschow, F.R.de Boer, J.Magn. Magn. Mater., Effect of grain size and magnetocrystalline anisotropy on exchange coupling in nanocomposite two-phase Nd-Fe-B magnets., 223, 215(2001) |
[6] | D.H.Ping, K.Hono, S.Hirosawa, J.Appl. Phys., Partitioning of Ga and Co atoms in a Fe3B/Nd2Fe14B nanocomposite magnet. 83, 7769(1998) |
[7] | Z.M.Chen, H.Okumura, Q.Chen et al, J.Appl. Phys., Enhancement of magnetic properties of Nanocomposite Pr2Fe14B/α-Fe magnets by small substitution of Dy for Pr. 89, 2299(2001) |
[8] | W.Zhang, A.Inoue, J.Appl. Phys., Crystallization and hard magnetic properties of Fe-Co-Nd-Dy-B amorphous alloys with glass transition. 87, 6122(2000) |
[9] | X.Y.Xiong, K.Hono, S.Hirosawa, H.Kanekiyo, J.Appl.Phys., Effects of V and Si additions on the coercivity and microstructure of nanocomposite Fe3B/Nd2Fe14B magnets, 91, 9308(2002) |
[10] | O.Gutfleisch, A.Bollero, A.Handstein, J.Magn. Magn. Mater., Nanocrystalline high performance permanent magnets, 242~245, 1277(2002) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%