材料研究学报, 2000, 14(5): 513-516. doi: 10.3321/j.issn:1005-3093.2000.05.014
含钡硫铝酸盐水泥基高水材料的制备
常钧
1,
, 程新
2,
, 芦令超
3,
, 刘福田
{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"混合价态的锰氧化物Pr1-xCaxMnO3薄膜是近年来国际上超导体以及巨磁电阻领域的研究热点之一.本文采用化学溶液沉积方法在Pt/Ti/SiO2/Si基底上制备出Pr1-xCaxMnO3薄膜,降低了材料成本;前驱体中不使用鳌和剂,简化了工艺.采用XRD、FT-IR、SEM、AFM、EPMA以及俄歇探针仪等方法对所制备的薄膜进行了表征.结果表明,实验中以较低的温度实现了PCMO钙钛矿结构的晶化;薄膜平整光滑致密,各组分分布均匀,C杂质含量处于很低的水平.","authors":[{"authorName":"王群","id":"ea5db09b-8684-4231-866d-a6cc357ded88","originalAuthorName":"王群"},{"authorName":"董睿","id":"02ecf463-18c7-4489-ae0e-cfde6bfab14d","originalAuthorName":"董睿"},{"authorName":"陈立东","id":"f0daec26-a513-436f-bf2a-9a457f63a7a9","originalAuthorName":"陈立东"}],"categoryName":"|","doi":"","fpage":"1087","id":"358f6ab8-dc06-424d-9b4f-eadd95d8b6e7","issue":"5","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"09c9025f-f019-4a80-bf0a-46e3b3c1af28","keyword":"混合价锰氧化物","originalKeyword":"混合价锰氧化物"},{"id":"5d7346f2-8cf8-4605-8f95-2288449de59a","keyword":" film","originalKeyword":" film"},{"id":"e5de067b-9719-486c-b1d7-9a65a3e11a4a","keyword":" chemical solution deposition method","originalKeyword":" chemical solution deposition method"}],"language":"zh","publisherId":"1000-324X_2004_5_3","title":"用化学溶液沉积方法制备Pr0.7Ca0.3MnO3薄膜","volume":"19","year":"2004"},{"abstractinfo":"混合价态的锰氧化物Pr1-xCaxMnO3 薄膜是近年来国际上超导体以及巨磁电阻领域的研究热点之一.本文采用化学溶液沉积方法在Pt/Ti/SiO2/Si基底上制备出Pr1-xCaxMnO3薄膜, 降低了材料成本; 前驱体中不使用鳌和剂, 简化了工艺.采用XRD、FT-IR、SEM、AFM、EPMA以及俄歇探针仪等方法对所制备的薄膜进行了表征.结果表明, 实验中以较低的温度实现了PCMO钙钛矿结构的晶化; 薄膜平整光滑致密, 各组分分布均匀, C杂质含量处于很低的水平.","authors":[{"authorName":"王群","id":"8a1d914f-8fbc-49ed-acc0-60ea2bd01a92","originalAuthorName":"王群"},{"authorName":"董睿","id":"f61330fe-7523-4cdd-9082-0ad238d5ce76","originalAuthorName":"董睿"},{"authorName":"陈立东","id":"44cafeb4-1d7f-4f18-aa37-5fd7d5768d5c","originalAuthorName":"陈立东"}],"doi":"10.3321/j.issn:1000-324X.2004.05.019","fpage":"1087","id":"66963235-6f32-44b3-9da4-8ee24b7a4b5f","issue":"5","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"964c536d-df4f-475a-be6b-fdd18ff0a257","keyword":"混合价锰氧化物","originalKeyword":"混合价锰氧化物"},{"id":"a35b4e8f-25a9-4988-af8e-681a81730093","keyword":"薄膜","originalKeyword":"薄膜"},{"id":"50a6e8cb-7510-4946-ab63-ae84f0cd2e3d","keyword":"化学溶液沉积法","originalKeyword":"化学溶液沉积法"}],"language":"zh","publisherId":"wjclxb200405019","title":"用化学溶液沉积方法制备Pr0.7Ca0.3MnO3薄膜","volume":"19","year":"2004"},{"abstractinfo":"采用传统固相法分别利用不同价态的MoO3和MoO2原料制备了Mo掺杂Mn位的La0.7Sr0.15 Ca0.15MnO3材料,主要利用光电子能谱和X射线吸收谱研究了过渡金属元素的电子结构特征和化学价态的不同.结果表明:用两种价态的Mo原料制备的钙钛矿锰氧化物体系的Mo离子价态表现不同,MoO2制备的材料体系价态偏低.同时,该变化还引起了Mn离子电子结构变化以及氧原子轨道能级与周围配位原子能级杂化强度的不同,这些内在电子结构的不同将成为材料表现出不同物理属性的可能原因.","authors":[{"authorName":"张红光","id":"99bb8436-fb75-4d59-b76a-d1244b732ce0","originalAuthorName":"张红光"},{"authorName":"张文浩","id":"62e4a8cf-2720-484d-a911-c0cc11cc279d","originalAuthorName":"张文浩"},{"authorName":"李恺","id":"3600324f-0037-4744-b146-4ac0c3613d81","originalAuthorName":"李恺"},{"authorName":"冯涛","id":"68616033-e32a-4888-85e2-6f3e45f57463","originalAuthorName":"冯涛"},{"authorName":"李永涛","id":"f87b190a-48a2-42d5-8d98-1acdbf6c7e79","originalAuthorName":"李永涛"},{"authorName":"刘胜利","id":"d8f8f393-7c3b-4050-8aeb-0fa79e2ef3d9","originalAuthorName":"刘胜利"},{"authorName":"谢亮","id":"9ca0a978-2291-4ff7-a293-fd1836d6d78d","originalAuthorName":"谢亮"}],"doi":"10.11896/j.issn.1005-023X.2014.22.018","fpage":"76","id":"aa463895-d6ac-4528-aed2-ef3ee3a1417f","issue":"22","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"1a6b085d-3d8f-45fd-8624-7ed2c09502f5","keyword":"钙钛矿锰氧化物","originalKeyword":"钙钛矿锰氧化物"},{"id":"714bc673-5c97-44a7-9c12-05a1432f7b7f","keyword":"固相反应法","originalKeyword":"固相反应法"},{"id":"c92c8cca-586a-4427-8b5c-9b57c5d3b19a","keyword":"光电子能谱","originalKeyword":"光电子能谱"},{"id":"ef8a76ae-0568-49ca-9d54-36a43327afcc","keyword":"X射线吸收谱","originalKeyword":"X射线吸收谱"},{"id":"6ded57f7-1159-4888-8f8b-7733f6941630","keyword":"化学价态","originalKeyword":"化学价态"}],"language":"zh","publisherId":"cldb201422018","title":"钼掺杂镧钙锶锰氧化物的化学价态和电子结构","volume":"28","year":"2014"},{"abstractinfo":"隧道构造锰氧化物在比表面、离子交换性、稳定性及分子级的隧道空间等方面具有优异的性能,其在催化剂、锂锰二次电池正极材料及吸附剂等材料科学领域的应用研究越来越受到人们的关注.综述了国内外隧道构造锰氧化物合成及应用的研究进展.","authors":[{"authorName":"崔浩杰","id":"ecbf0859-7ca9-46ec-82cb-f00387839852","originalAuthorName":"崔浩杰"},{"authorName":"冯雄汉","id":"63390bfb-139f-4a9b-9457-4ab2c131f30b","originalAuthorName":"冯雄汉"},{"authorName":"谭文峰","id":"77f11106-f28a-4ce2-8d3b-eba0a03c3707","originalAuthorName":"谭文峰"},{"authorName":"刘凡","id":"db9399ef-a5f1-442e-846f-619ae6b97b37","originalAuthorName":"刘凡"}],"doi":"","fpage":"277","id":"6c4005c2-7751-4f4b-a9f4-6244e022a23d","issue":"z2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"21ef2db8-191a-4031-a56b-c16f305016b1","keyword":"锰氧化物","originalKeyword":"锰氧化物"},{"id":"883944e2-62b9-4e7c-914e-7ea4fb5ea8a8","keyword":"合成","originalKeyword":"合成"},{"id":"13546eb0-623b-4a2d-861b-1fd6b3c05390","keyword":"隧道构造","originalKeyword":"隧道构造"}],"language":"zh","publisherId":"cldb2004z2084","title":"隧道构造锰氧化物合成及应用","volume":"18","year":"2004"},{"abstractinfo":"综述了过渡金属锰氧化物作为稳定剂制备稳定氧化锆的研究现状及其物理性能,简单介绍了过渡金属Mn掺杂氧化锆基固溶体的基本特性,如Mn在ZrO2中的溶解度、价态变化及其对氧化锆晶格常数的影响,以及其催化性、导电性、磁性能、应用,并展望了今后的研究方向.","authors":[{"authorName":"高玲","id":"808d21dc-ee16-4244-841e-bcfce08e56b3","originalAuthorName":"高玲"},{"authorName":"周廉","id":"59416bba-f0a1-45f5-95c0-30f308ababc5","originalAuthorName":"周廉"},{"authorName":"冯建情","id":"46ae7352-9a98-483c-beba-f0d46e03027a","originalAuthorName":"冯建情"},{"authorName":"李成山","id":"cadd4fa7-4616-4b37-bdd1-5404d8a282c3","originalAuthorName":"李成山"},{"authorName":"卢亚锋","id":"22a18554-2023-4347-947d-731f2865ae52","originalAuthorName":"卢亚锋"}],"doi":"","fpage":"43","id":"c2d8b932-f2ce-495e-ae9c-affa6f316e3a","issue":"1","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"ffa51a64-00af-41ab-8b49-5e0c9bb3eea0","keyword":"稳定氧化锆","originalKeyword":"稳定氧化锆"},{"id":"f31eeb0c-3fa9-46ab-9068-ad3f7f4ad3a6","keyword":"锰氧化物","originalKeyword":"锰氧化物"},{"id":"67a8437a-728c-4401-888e-7a881d13624e","keyword":"固溶体","originalKeyword":"固溶体"},{"id":"ba056e4e-25d1-4b28-876c-91470d2879ef","keyword":"物理性能","originalKeyword":"物理性能"}],"language":"zh","publisherId":"cldb201201010","title":"锰氧化物稳定氧化锆的研究现状","volume":"26","year":"2012"},{"abstractinfo":"以乙酸铜和乙酸锰为铜锰前驱体,以NH4HCO3为沉淀剂,相应金属硝酸盐为掺杂剂,采用共沉淀法制备了不同过渡金属氧化物掺杂的铜锰氧化物催化剂.采用N2物理吸附、X射线衍射,氢气-程序升温还原和原位红外漫反射光谱等方法对催化剂进行了表征,考察了系列催化剂上CO反应性能.结果表明,掺杂过渡金属氧化物可以调变催化剂对CO的吸附能力,进而影响催化剂性能.","authors":[{"authorName":"蔡丽娜","id":"e4495e15-6451-4016-b297-8a65c4155998","originalAuthorName":"蔡丽娜"},{"authorName":"胡臻皓","id":"4b74cdfe-0009-46a6-8ed1-0d62f345eec5","originalAuthorName":"胡臻皓"},{"authorName":"","id":"196e7937-34bb-4ab4-aea0-ff7bd9d08ab7","originalAuthorName":""},{"authorName":"李文翠","id":"2b8e1a4e-7b9f-432b-9b42-670e6ecda333","originalAuthorName":"李文翠"}],"doi":"10.1016/S1872-2067(12)60699-8","fpage":"159","id":"10fbabac-6b55-4987-84eb-04bac73f1f21","issue":"2","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"3d193a97-cb4f-4318-9d6a-c60c608804a4","keyword":"铜锰氧化物","originalKeyword":"铜锰氧化物"},{"id":"811c6abb-03c8-4362-8087-328af9dca88a","keyword":"过渡金属氧化物","originalKeyword":"过渡金属氧化物"},{"id":"574254df-1571-42f0-9a38-154d32bb656a","keyword":"掺杂","originalKeyword":"掺杂"},{"id":"61aeec24-1c96-4871-b6c4-7ea47cb27d48","keyword":"一氧化碳氧化","originalKeyword":"一氧化碳氧化"},{"id":"c07dd4c3-4b41-4a7a-acb2-82fe58b9967e","keyword":"原位红外漫反射光谱","originalKeyword":"原位红外漫反射光谱"}],"language":"zh","publisherId":"cuihuaxb201402001","title":"过渡金属氧化物掺杂对铜锰氧化物催化CO氧化性能的影响","volume":"35","year":"2014"},{"abstractinfo":"研制了一种新型稀土氧化物混合物防雾剂,其由表面活性剂、添加剂、分散剂和稀土混合物混合而成.考察了其防雾效果及透光率,并与现有产品进行比较.结果显示,本防雾剂防雾效果很好,不影响玻璃的透光率,配方简单,容易生产,防雾性能优于其它产品.","authors":[{"authorName":"熊丽萍","id":"21fde709-ee60-479d-886b-5f31e4d17e8b","originalAuthorName":"熊丽萍"},{"authorName":"何忠义","id":"31621525-42dd-49a1-83e6-7c37d063cfaf","originalAuthorName":"何忠义"},{"authorName":"刘红","id":"bc3a3c08-ca1d-4798-a985-02b5e593bed0","originalAuthorName":"刘红"}],"doi":"10.3969/j.issn.1004-0277.2007.03.014","fpage":"55","id":"bc75aec3-884f-4689-94c6-0426eed13131","issue":"3","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"49fe9553-8042-4c8e-989c-9b34f466a064","keyword":"超细稀土混合物","originalKeyword":"超细稀土混合物"},{"id":"772c2ff5-e758-48b5-90b6-588262ab2f6a","keyword":"玻璃防雾剂","originalKeyword":"玻璃防雾剂"},{"id":"5701aafc-ca19-45a4-a5a0-5d59761ded48","keyword":"研制","originalKeyword":"研制"}],"language":"zh","publisherId":"xitu200703014","title":"新型混合稀土氧化物防雾剂的研制","volume":"28","year":"2007"},{"abstractinfo":"孔径从微孔到介孔的多孔锰氧化物材料有多种制备方法.不同的制备方法,材料的性能有所不同.多孔锰氧化物材料在可充锂电池、高级分离技术、化学传感、催化以及环保等领域有潜在的重要应用价值.综述了多孔锰氧化物材料在结构、制备和性能等方面的研究进展.","authors":[{"authorName":"王永在","id":"c3a2ecad-0ef6-45a5-b5b1-b14bb0f35909","originalAuthorName":"王永在"},{"authorName":"廖立兵","id":"1b7e662e-ceda-4e9a-9ac1-25d6fde67737","originalAuthorName":"廖立兵"},{"authorName":"黄振宇","id":"06db1be6-b72a-403c-8ac2-cf4b07447182","originalAuthorName":"黄振宇"}],"doi":"","fpage":"43","id":"8f98f0d3-f9a5-455e-9346-111ee79fef8d","issue":"6","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"1764c2cb-7442-4a02-915c-a8ad35ade792","keyword":"多孔锰氧化物","originalKeyword":"多孔锰氧化物"},{"id":"14af6b5b-c3b4-4731-9dee-bf56f24b43f0","keyword":"制备方法","originalKeyword":"制备方法"},{"id":"6d12540b-d772-4128-aa60-df55c19500b0","keyword":"性能及应用","originalKeyword":"性能及应用"}],"language":"zh","publisherId":"cldb200406013","title":"多孔锰氧化物材料的制备与性能研究进展","volume":"18","year":"2004"},{"abstractinfo":"尖晶石型锂锰氧化物是目前最具发展前景的锂吸附剂.介绍了锂锰氧化物的合成方法及结构、Li+的抽提/嵌入反应机理和锂离子筛吸附锂过程中的影响因素,讨论了对目前在锂吸附剂的制备及实际应用等方面存在的问题,并展望了锂锰氧化物离子筛未来的研究方向.","authors":[{"authorName":"綦鹏飞","id":"e9cfe8b7-1adf-41e8-b5b8-897d25e11673","originalAuthorName":"綦鹏飞"},{"authorName":"朱桂茹","id":"c60fab8c-ff62-4c37-81e2-e4f6bb4f9ffd","originalAuthorName":"朱桂茹"},{"authorName":"王铎","id":"4a8d7a86-7666-4672-b1a8-d31557194a6a","originalAuthorName":"王铎"},{"authorName":"高从楷","id":"5d912b78-fb48-4653-8b1c-ff026bf5c918","originalAuthorName":"高从楷"}],"doi":"","fpage":"303","id":"b4d9abd7-c4dd-4583-9575-53d8d41d659a","issue":"z2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"d31a61db-2706-475a-8ab9-65684107fb1a","keyword":"锂锰氧化物","originalKeyword":"锂锰氧化物"},{"id":"d4249f79-ea1a-40d2-a7a4-8707054017db","keyword":"离子筛","originalKeyword":"离子筛"},{"id":"8bc26f62-7449-48a2-a5fb-e68f10113f27","keyword":"吸附","originalKeyword":"吸附"}],"language":"zh","publisherId":"cldb2009z2091","title":"锂锰氧化物离子筛的研究进展","volume":"23","year":"2009"},{"abstractinfo":"电荷有序现象在混价过渡金属氧化物中早有研究, 钙钛矿锰氧化物中由于电荷有序与自旋有序、轨道有序、晶格畸变等相互关联而特别引人注目. 本文综述了有关电荷有序现象的早期
研究与近期进展, 重点介绍了电荷有序转变附近的一些物理异常现象与影响电荷有序态稳定的有关因素.","authors":[{"authorName":"陈春霞","id":"097aae24-cc7f-4bd0-9ebe-3f00cbcc9871","originalAuthorName":"陈春霞"}],"categoryName":"|","doi":"","fpage":"1","id":"4fe106d0-54c7-42f7-8a1b-18c580ac0c46","issue":"1","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"a0a86806-965f-4200-82ba-1b0aeb0ad3f4","keyword":"锰氧化物","originalKeyword":"锰氧化物"},{"id":"760e0462-359d-41b4-a41c-9f003748fda7","keyword":" charge ordering","originalKeyword":" charge ordering"}],"language":"zh","publisherId":"1000-324X_2005_1_23","title":"钙钛矿锰氧化物中电荷有序现象研究进展","volume":"20","year":"2005"}],"totalpage":6472,"totalrecord":64713}