报道了尿及河底泥中环境雌激素(壬基酚、双酚A、己烯雌酚、17α-乙炔基雌二醇)和内源性雌激素(17α-雌二醇、17β-雌二醇、雌三醇、雌酮)的气相色谱-质谱(GC-MS)测定法.尿样经盐酸溶液水解后用固相萃取(SPE)柱浓缩净化,底泥样品用甲醇-乙酸乙酯萃取.被测组分经五氟丙酸酐(PFPA)衍生化后用GC-MS进行定性定量检测.该法测定的峰面积的日内相对标准偏差为1.22%～5.55%,检出限为0.05～1.27 μg/L(或μg/kg).被测组分的加标回收率除尿样中17α-乙炔基雌二醇和己烯雌酚分别为25.4%和71.0%外,其余为86.7%～111.2%.
参考文献
| [1] | Jiang Xuezhi. China Public Health, 1997, 13(4): 251蒋学之. 中国公共卫生, 1997, 13(4): 251 |
| [2] | González-Casado A, Navas N, Del Olmo M, Vilchez J L. J Chromatographic Sci, 1998, 36(11): 565 |
| [3] | Lee H B, Peart T E. J AOAC Int, 1998, 81(6): 1209 |
| [4] | Kelly C. J Chromatogr A, 2000, 872: 309 |
| [5] | Nakamura S, Hwee Sian T, Daishima S. J Chromatogr A, 2001, 919: 275 |
| [6] | Helaleh I H M, Fujii S, Korenaga T. Talanta, 2001, 54: 1039 |
| [7] | Xiao X Y, McCalley D V, McEvoy J. J Chromatogr A, 2001, 923: 195 |
| [8] | Pedersen S N, Lindholst C. J Chromatogr A, 1999, 864: 17 |
| [9] | de Alda J M L, Barceló D. J Chromatogr A, 2000, 892: 391 |
| [10] | Zhang Hong, Guo Dacheng, Sun Chengjun. Physical Testing and Chemical Analysis, Part B: Chemical Analysis, 2002, 38(8): 379张宏, 郭大城, 孙成均. 理化检验, B: 化学分册, 2002, 38(8): 379 |
| [11] | Sun Y, Wada M, Kuroda N, Hirayama, Nakazawa H, Nakashima K. Anal Sci, 2001, 17: 697 |
| [12] | Helaleh M L H, Tanaka K, Fujii S-I, Korenaga T. Anal Sci, 2001, 17: 1225 |
| [13] | Petervic M, Barcelo D. J AOAC Int, 2001, 84: 1074 |
| [14] | Edman K, Sevensson L, Eriksson B, Gunnarsson P O. J Chromatogr B, 2000, 738: 267 |
| [15] | Watanabe T, Yananoto H, Inoue K, Yamaguchi A, Yoshimura Y, Kato K, Naotaka H, Nakashima K. J Chromatogr B, 2001, 762: 1 |
| [16] | Sajiki J. J Chromatogr B, 2001, 755: 9 |
| [17] | Casademont G, Perez B, Regueiro J A G. J Chromatogr B, 1996, 686: 189 |
| [18] | Tsukioka T, Brock J, Graiser S, Nguyen J, Nakazawa H, Makino T. Anal Sci, 2003, 19: 151 |
| [19] | Choi M H, Kim K R, Chung B C. Analyst, 2000, 125: 711 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%