基于双势阱模型,利用蒙特卡罗随机模拟法,采用偶极子系统不同构成方式研究了以高分子聚合物为基料、纳米颗粒掺杂所形成的复合材料的特殊介电性能,即剩余极化和快松弛现象.研究表明:偶极子系统可以模拟不同电介质材料的微观构成,其对外加激励的响应能反映所研究材料的介电特性,而系统趋于稳定的迭代过程可以表征材料在外电场中的极化松弛速率.本文的模拟结果与文献报道一致,该方法为研究材料介电特性提供了一种简便有效的技术手段,并可作为实验室开发具有特殊性能新型介质材料的辅助工具.
参考文献
[1] | 南策文.从非常规复合效应产生新型材料[J].自然科学进展,2004,14(4):390-396.Nan Cewen.A creation of new materials from nonintuition composite effect[J].Progress in Nature Science,2004,14(4):390-396. |
[2] | Robertson J,Varlow B R.Non-linear ferroelectric composite dielectric materials[J].IEEE Transactions on Dielectrics and Electrical Insulation,2005,12(4):779-789. |
[3] | 党智敏,王海燕,王岚.新型高温高介无机-有机功能复合材料[J].复合材料学报,2005,22(5):9-15.Dang Zhimin,Wang Haiyan,Wang Lan.New inorganic/organic functional composites with high temperature and high dielectric constant[J].Acta Materiae Compositae Sinica,2005,22(5):9-15. |
[4] | Khalil M S.The role of BaTiO3 in modifying the dc breakdown strength of LDPE[J].IEEE Transactions on Dielectrics and Electrical Insulation,2000,7(2):261-268. |
[5] | 季光明,陶杰,汪涛,杨斌鹏.纳米TiO2填充改性PP的力学性能研究[J].复合材料学报,2005,22(5):100-106.Ji Guangming,Tao Jie,Wang Tao,Yang Binpeng.Investiga tion on the mechanical properties of nano-TiO2/PP composites[J].Acta Materiae Compositae Sinica,2005,22 (5):100-106. |
[6] | EI-Hag A H,Simon L C,Jayaram S H,et al.Erosion resist ance of nano-filled silicone rubber[J].IEEE Transactions on Dielectrics and Electrical Insulation,2006,13(1):122-128. |
[7] | Cherney E A.Silicone rubber dielectrics modified by inorganic fillers for outdoor high voltage insulation applications[J].IEEE Transactions on Dielectrics and Electrical Insulation,2005,12(6):1108-1115. |
[8] | 孙举涛,黄玉东,曹海琳.Co3O4纳米粒子的表面改性及其对复合材料性能的影响[J].复合材料学报,2004,21(3):33-37.Sun Jutao,Huang Yudong,Cao Hailin.Effects of surface treatment of Co3O4 nano-particles on the properties of the IR nanocomposites[J].Acta Materiae Compositae Sinica,2004,21(3):33-37. |
[9] | Lewis T J.Interfaces at the dominant feature of dielectrics at the nanometric level[J].IEEE Transactions on Dielectrics and Electrical Insulation,2004,11(5):739-753. |
[10] | 唐春安,傅宇方,朱万成.界面性质对颗粒增强复合材料破坏模式影响的数值模拟分析[J].复合材料学报,1999,16(4):112-120.Tang Chun'an,Fu Yufang,Zhu Wancheng.Numerical approach to effect of interface properties on failure modes in particle filled composite[J].Acta Materiae Compositae Sinica,1999,16(4):112-120. |
[11] | 关志东,郭渊.含缺陷的复合材料层合板低速冲击过程的有限元模拟[J].复合材料学报,2006,23(2):180-184.Guan Zhidong,Guo Yuan.Computer simulation of low-veloci ty impact process of the composite laminate with defect[J].Acta Materiae Compositae Sinica,2006,23(2):180-184. |
[12] | Wagner A,Kliem H.Dispersive ionic space charge relaxation in solid polymer electrolytes Ⅱ:Model and simulation[J].Journal of Applied Physics,2002,91(10):6638-6649. |
[13] | Kuehn M,Kliem H.Simulation of heterogeneous nanódielectrics using the local field method[J].IEEE Transactions on Dielectrics and Electrical Insulation,2005,12(4):844-853. |
[14] | Farag N,Kliem H.Ferroelectric hysteresis in system of permanent dipoles:A computer simulation[J].Ferroelectrics,1999,228(1/4):197-218. |
[15] | 金维芳.电介质物理学[M].第2版.北京:机械工业出版社,1995:35-41.Jin Weifang.The dielectric physics[M].The 2nd version.Beijing:China Machine Press,1995:35-41. |
[16] | Lewis T J.Ageing--A perspective[J].IEEE Electrical Insulation Magazine,2001,17(4):6-16. |
[17] | 王力衡.介质的热刺激理论及其应用[M].北京:科学出版社,1988:51-85.Wang Liheng.Theory and application of thermally stimulated current in dielectrics[M].Beijing:Science Press,1988:51-85. |
[18] | Farag N,Kliem H.Computer-aided modeling of dielectric and ferroelectric properties[J].IEEE Electrical Insulation Maga zine,1999,15(3):25-31. |
[19] | Farag N,Kliem H.Ferroelectricity in system of induced and permanent dipoles:A Monte Carlo study[J].Journal of Ap plied Physics,2001,90(11):5713-5720. |
[20] | Kliem H.Dielectric small-signal response by protons in amorphous insulators[J].IEEE Transactions on Electrical Insulation,1989,24(2):185-197. |
[21] | Kliem H,Fuhrmann P,Arlt A.A numerical method for the determination of first-order kinetics relaxation time spectra[J].IEEE Transactions on Electrical Insulation,1988,23(6):919-927. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%