介绍了聚环氧乙烷(PEO)/LixV2-δO4-δ纳米复合材料的制备工艺过程.通过X射线衍射、示差扫描量热分析、红外光谱等仪器进行分析,结果表明,PEO大分子插入到LixV2δO4-δ片层间,使层间距增大了0.42 nm,并且PEO在片层间的运动能力受到了一定的限制.
参考文献
| [1] | Lee D C, Jang L W. Preparation and characterization of PMMA-clay hybrid composite by emulsion polymerization [J]. J Appl Polym Sci, 1996,61(7): 1117-1122. |
| [2] | Furuichi N, Kurokawa Y, Fujita K. Preparation and properties of polypropylene reinforced by smectite[J]. J Mater Sci, 1996,31(16): 4307 4310. |
| [3] | Akelan A, Moet A. Polymer-clay nanocom:free radical grafting of polystyrene on to organophilic montmorillonite[J]. J Mater Sci, 1996,31(13): 3589-3596. |
| [4] | Wang S, Li Q, Qi Z. Studies on silicone rubber/montmorillonite hybrid composites [J ]. Key Eng Mater, 1998, 137 ( 2 ): 87-93. |
| [5] | Lemmon J P, Lemer M M. Preparation of nanocomposites of poly(ethylene oxide) with TiS2[J]. Solid State Commun, 1995,94(7): 533-537. |
| [6] | Messersmith P B, Giannelis E P. Synthesis and characterization of layered silicate-epoxy nanocomposites [J ]. Chem Mater, 1994,6(10): 1719-1725. |
| [7] | 宋国君.舒文艺.聚合物基纳米复合材料[J].材料导报.1996,2(4):57-60. |
| [8] | Kannewurf C R, Kanatzidis M G. Intercalation of poly(ethylene oxide) in V2O5 xerogel[J]. Chem Mater, 1991, 3(6): 992-994. |
| [9] | WangL, Schindler J, Albritton J, et al. Entrapment of polypyrrole chains between MoS2 layer via an in situ oxidative polymerization encapsulation reaction[J]. Chem Mater, 1995,7(10): 1753-1755. |
| [10] | Nazar L F, Zhang Z, Zinkweg D. Insertion of poly(p-phenylene vinylene) in layered MoO3[J]. J Am Chem Soc, 1992, 114:6239-6240. |
| [11] | Bissessur R, De Groot D C, Kannewurf C. Inclusion of Poly (aniline) into MoO3[J]. J Chem Soc Commun, 1993, 687-689. |
| [12] | Bissessur R, Kanatzidis M G, Schindler J L. Encapsulation of polymer into MoS2 and metal to insulator transition metastable MoS2lJ]. J Chem Soc, Chem Commun, 1993,1582-1585. |
| [13] | Ruiz-Hitzky E, Aranda P. Poly(ethylene oxide)-silicate intercalation materials[J]. Chem mater, 1992, 4(6): 1395-1403. |
| [14] | Chatani Y, Okamura S. Crystal structure of poly (ethylene oxide)-sodium iodide complex [J]. Polymer, 1987, 28 ( 11 ):1815. |
| [15] | Blumberg A, Pollack S S. A PEO-mercuric chloride complex[J]. J Polym Sci, Part A,1964,2(5),2499-2502. |
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