高钨铸造合金已用于铸造大型模具,由于大量初生M6C碳化物的形成使模具变脆,需探明初生M6C的形成条件.实验表明当含碳量超过0.15%时,合金中易析出初生M6C,而10%Co起有效的抑制作用.初生M6C是在1375℃时形成的,它对通过固-液范围的冷却速度十分敏感,快冷抑制它的形成.铸件中M6C的形成存在明显的尺寸效应,枝晶间距大于150μm 时的较厚截面极易形成毫米量级的M6C,严重的损伤合金的高温强度.因此对大截面的模具合金,为防止初生M6C的析出,合金中最好保持0.04%-0.07%C和10%-15%Co.
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