采用静电纺丝法制得 La2CoFeO6竹节状中空纳米纤维光催化材料。La2CoFeO6纳米纤维具有稳定的一维结构,由菱形晶型的La2CoFeO6纳米颗粒相互连接组成,并存在明显的竹节状中空结构,其比表面积可达98.7 m2/g。La2CoFeO6纳米纤维对自然光具有较高的利用率,其禁带宽度为1.6 eV。在甲基橙溶液浓度为10 mg/L, pH为2,催化剂用量为1.5 g/L条件下,自然光光照2 h后, La2CoFeO6纳米纤维对甲基橙的降解率可达96.9%。
La2CoFeO6 bamboo-like hollow nanofibers photocatalytic material was successfully prepared by elec-trostatic spinning. La2CoFeO6 nanofibers, which were connected to each other by rhombic La2CoFeO6 nanoparticles, had stable one-dimensional structure and clear bamboo-like hollow structure. The specific surface area of as-prepared inorganic nanofibers reached 98.7 m2/g. La2CoFeO6 nanofibers had a high utilization for natural light and its band gap was 1.6 eV. When concentration of methyl orange was 10 mg/Lwith pH of 2 and the dosage of La2CoFeO6 nanofibers was 1.5 g/L, methyl orange was degraded by La2CoFeO6 nanofibers within 2 h under natural light at 96.9%.
参考文献
[1] | 曲晓飞;刘鲁英;李雪钦;杜芳林.Er3+掺杂TiO2空心球的制备及其光催化性能研究[J].无机材料学报,2015(2):183-188. |
[2] | Satoru Inoue;Masanori Kawai;Noriya Ichikawa.Anisotropic oxygen diffusion at low temperature in perovskite-structure iron oxides[J].Nature Chemistry,20103(3):213-217. |
[3] | Tien-Thao N;Alamdari H;Zahedi-Niaki MH;Kaliaguine S.LaCo1-xCuxO3-delta perovskite catalysts for higher alcohol synthesis[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,20060(0):204-212. |
[4] | 异质结型BaTiO3/TiO2复合纳米纤维的制备及光催化性能[J].无机材料学报,2014(07):741-746. |
[5] | G. Kim;S. Wang;A. J. Jacobson.Rapid oxygen ion diffusion and surface exchange kinetics in PrBaCo2O_(5+x) with a perovskite related structure and ordered A cations[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200724(24):2500-2505. |
[6] | 吴艳波;毕军;魏斌斌.双钙钛矿La2CoNiO6无机纳米纤维的制备及超级电容器性能[J].物理化学学报,2015(2):315-321. |
[7] | Iwakura, H.;Einaga, H.;Teraoka, Y..Relationship between cation arrangement and photocatalytic activity for Sr-Al-Nb-O double perovskite[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,201024(24):11362-11369. |
[8] | Li DF;Zheng J;Zou ZG.Band structure and photocatalytic properties of perovskite-type compound Ca2NiWO6 for water splitting[J].The journal of physics and chemistry of solids,20064(4):801-806. |
[9] | Kodambaka S;Tersoff J;Reuter MC;Ross FM.Germanium nanowire growth below the eutectic temperature[J].Science,20075825(5825):729-732. |
[10] | Huan-Chun Wang;Yuan-Hua Lin;Yan-Nan Feng;Yang Shen.Photocatalytic behaviors observed in Ba and Mn doped BiFeO_3 nanofibers[J].Journal of electroceramics,20131/2(1/2):271-274. |
[11] | Pengrong Ren;Huiqing Fan;Xin Wang.Electrospun nanofibers of ZnO/BaTiO_3 heterostructures with enhanced photocatalytic activity[J].Catalysis Communications,2012:32-35. |
[12] | Bo Dong;Zhicheng Li;Zhenyu Li;Xiuru Xu;Mingxin Song;Wei Zheng;Ce Wang;Salem S. Al-Deyab;Mohamed El-Newehy.Highly Efficient LaCoO_3 Nanofibers Catalysts for Photocatalytic Degradation of Rhodamine B[J].Journal of the American Ceramic Society,201011(11):3587-3590. |
[13] | Shudan Li;Liqiang Jing;Wei Fu;Libin Yang;Baifu Xin;Honggang Fu.Photoinduced charge property of nanosized perovskite-type LaFeO_3 and its relationships with photocatalytic activity under visible irradiation[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,20072(2):203-212. |
[14] | Lishan Jia;Juanjuan Li;Weiping Fang.Enhanced visible-light active C and Fe co-doped LaCoO3 for reduction of carbon dioxide[J].Catalysis Communications,20092(2):87-90. |
[15] | K.M. Parida;K.H. Reddy;S. Martha;D.P. Das;N. Biswal.Fabrication of nanocrystalline LaFeO_3: An efficient sol-gel auto-combustion assisted visible light responsive photocatalyst for water decomposition[J].International journal of hydrogen energy,201022(22):12161-12168. |
[16] | Lishan Jia;Juanjuan Li;Weiping Fang.Visible-light-induced photocatalyst based on C-doped LaCoO3 synthesized by novel microorganism chelate method[J].Catalysis Communications,20098(8):1230-1234. |
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