采用EPMA、XRD、TEM等手段分析了压水堆核电站主管道用Fe20Cr9Ni铸造奥氏体不锈钢中σ相的成分和结构,通过等温时效处理、金相组织分析,研究了σ相析出动力学,获得了σ相析出的时间-温度-转变(TTT)曲线及JMA析出动力学方程.研究结果表明:Fe20Cr9Ni中σ相析出的温度范围为600～840℃,750℃时σ相析出动力学最快,600～750℃时σ相的析出量计算值与实验值符合得较好.σ相形成激活能为149kJ/mol,接近Cr在铁素体中的扩散激活能值,其过程主要受Cr扩散控制.Fe20Cr9Ni铸造奥氏体不锈钢中σ相析出特征主要由其特殊的合金成分和组织结构决定.
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