通过对BOF-Ar站-CC炼钢流程生产低碳铝镇静钢的中间包不同浇注时间取样及正常坯的取样,采用氧氮化学分析、光学显微镜以及扫描电镜-能谱(SEM+EDS)等多种方法研究了中间包浇注过程夹杂物特征的变化.结果表明:每炉钢包开浇时与浇注末期,钢中T[O]含量均高于浇注中期的T[O]含量,这是由于换包过程中钢水被二次氧化;中间包钢水及正常坯中的夹杂物,按照其形貌与成分可以分为以下3类:Al2O3基夹杂物,MnS基夹杂物,来自中间包覆盖剂或者钢包下渣所卷入的外来夹杂物.中间包及铸坯中的夹杂物主要以1-4 μm的Al2O3为主,同时在铸坯中发现了大量的MnS夹杂物,使铸坯中夹杂物的数量密度升高.当钢液中硫含量较高时,铸坯中气泡+Al2O3类型的夹杂物增加.在当前的工艺条件下,交换钢包之后的开浇阶段与浇注末期,钢水的二次氧化对铸坯的洁净度产生重要影响,同时应合理控制钢中的硫含量,减少铸坯中气泡+Al2O3类型的夹杂物,避免钢液在凝固过程中析出大量的MnS夹杂物.
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