以正硅酸乙酯改性的磷酸二氢铝为黏结剂、铬酸镁为钝化剂、铝粉为填料制备了水性含铝磷酸盐涂料,随后喷涂于300M高强钢上制备了含铝磷酸盐防腐涂层,研究了该涂层在中性盐雾中的耐腐蚀性能以及抗高温氧化性能.结果表明:该涂层表面较为致密、平整,在中性盐雾中腐蚀1000 h后,涂层表面无腐蚀产物形成;在600℃氧化100 h 后,涂层表面保持完整,其单位面积氧化质量增加为8.0517 g.m-2,远小于300M高强钢的(23.8111 g.m-2),氧化速率也低于高强钢的,涂层具有良好的抗高温抗氧化性.
Using tetraethyl orthosilicate modified aluminum dihydrogen phosphate as binder,magnesium dichromate as passivator and aluminum powder as filler,the water-borne aluminum containing phosphate coating solution was prepared.Then the anti-corrosion aluminum containing phosphate coating was obtained by spraying the coating solution on 300M high-strength steel.The corrosion resistance in neutral salt spray and the high temperature oxidation resistance of the coating were investigated.The results show that the coating surface was dense and flat. After corrosion in the neutral salt spray for 1 000 h,no corrosion products were formed on the coating surface.After oxidation at 600 ℃ for 100 h,the coating surface remained integrity and the oxidation mass increase per unit area was 8.051 7 g.m-2,which was much lower than that of 300M high-strength steel (23.811 1 g.m-2);the oxidation rate of the coating was also lower than that of the high-strength steel,indicating the excellent high-temperature oxidation resistance of the coating.
参考文献
[1] | 于美;董宇;王瑞阳;祁晋豫;刘建华;李松梅.23Co14Ni12Cr3Mo超高强钢在模拟海水环境中的腐蚀行为[J].材料工程,2012(1):42-50. |
[2] | Joseph H.Osborne;Kay Y.Blohowiak;S.Ray Taylor;Chad Hunter;Gordon Bierwagon;Brendon Carlson;Dan Bernard;Air force research laboratory nonmetallic mateirals directorate WPAFB OH 45433-7750 USA;Michael S. Donley.Testing and evaluation of nonchromated coating systems for aerospace applications[J].Progress in Organic Coatings: An International Review Journal,20014(4):217-225. |
[3] | B. Formanek;K. Szymariski;B. Szczucka-Lasota.New generation of protective coatings intended for the power industry[J].Journal of Materials Processing Technology,20050(0):850-855. |
[4] | 王政阅 .磷酸盐耐热涂层的制备及固化机理的研究[D].天津大学,2007. |
[5] | 王维.IPcote9183金属陶瓷涂层制备及其性能[J].腐蚀与防护,2011(6):480-482,493. |
[6] | 王志强;胥卫奇;王国志;腾瑞;刘文兴;李洁.含铝磷酸盐耐高温防腐蚀涂料制备及施工工艺的研究[J].现代涂料与涂装,2010(2):3-5. |
[7] | 冯莉;段慎修;刘辉.磷酸盐耐热涂料的研制[J].涂料工业,2002(8):14-16. |
[8] | Agüero, A.;del Hoyo, J.C.;García de Blas, J.;García, M.;Gutiérrez, M.;Madue?o, L.;Ulargui, S..Aluminum slurry coatings to replace cadmium for aeronautic applications[J].Surface & Coatings Technology,2012:229-238. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%