通过对某油田使用的 N80钢油管的化学成分、显微组织、腐蚀形貌和腐蚀产物进行分析,探讨了该油管腐蚀失效的原因。结果表明:该油管的主要腐蚀形式为局部腐蚀,外壁主要表现为大面积的点蚀,内壁主要表现为涂层破坏引起的严重局部腐蚀;腐蚀介质中的 O 2、Cl-和 S2-导致油管发生吸氧腐蚀、氯盐腐蚀和硫化物腐蚀,其中 Cl-为主要的腐蚀介质;S2 -和 Cl-的协同作用会加速腐蚀产物膜的破坏,从而导致腐蚀加剧。
Corrosion reasons for N80 steel tubing used in a oilfield were discussed by analyzing chemical composition, microstructure,corrosion morphology and corrosion products.The results show that the main corrosion forms of the tubing was local corrosion;outer wall showed a large area of pitting while inner wall manifested as severe local corrosion due to failure of corrosion coating.O2 ,Cl- and S2- in corrosion media caused oxygen-absorption corrosion,Cl- corrosion and sulfide corrosion,Cl- was the main corrosive media.Synergistic effect of S2- and Cl- accelerated the destruction of corrosion product film,and thus leading to corrosion accelerating.
参考文献
[1] | 马宗况;俞亚鹏;张文基;李国忠;沈建军;张勇钢;黄建凯;王成.非调质钢N80钢级油管及接箍料的开发[J].江苏冶金,2002(1):1-3,6. |
[2] | 牛靖;董俊明;薛锦;何兴利.石油套管钢N80的显微组织分析[J].焊管,2002(1):15-17. |
[3] | 曲鹏;侯庆平;王树人.石油套管用N80钢的研制[J].焊管,2009(5):15-17,21. |
[4] | 张强;杨文忠;唐永明;顾春元;周拾庆;仓辉;丁毅.N80钢在江苏油田水中的应力腐蚀行为研究[J].腐蚀与防护,2006(2):66-68. |
[5] | 周卫军;严密林;王成达.N80S抗硫油管钢在含CO2、微量H2S及高浓度Cl-腐蚀介质中的腐蚀行为[J].石油与天然气化工,2007(2):135-138. |
[6] | S Vishwanatham;Vishwanatham;N Haldar;Haldar.Furfuryl Alcohol As Corrosion Inhibitor For N80 Steel In Hydrochloric Acid[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,200811(11):2999-3004. |
[7] | 王霞;张仁勇;上官昌淮;陈勇彬.两种套管钢在含CO2模拟油田地层水中的腐蚀行为[J].机械工程材料,2013(5):69-72. |
[8] | 杨良杰;王喜茂;崔占东;孙淑东;陈伟君.冀东油田套管损坏现状及综合治理措施[J].石油钻采工艺,2003(2):79-82. |
[9] | 杨耀辉;徐忠苹;李凤;周巍;韩文礼;张旭.冀东南堡油田土壤环境腐蚀性研究[J].全面腐蚀控制,2012(5):26-29. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%